First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Hydride transfer reactions catalyzed by cobalt complexes

W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Overview of regioselective and stereoselective catalytic hydroboration of alkynes

S Rej, A Das, TK Panda - Advanced Synthesis & Catalysis, 2021 - Wiley Online Library
Hydroboration of alkynes is of special interest to researchers since it is the most
straightforward process for the synthesis of highly important vinylborane synthetic …

Alkenyl boronates: synthesis and applications

J Carreras, A Caballero… - Chemistry–An Asian …, 2019 - Wiley Online Library
Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

Emergence and applications of base metals (Fe, Co, and Ni) in hydroboration and hydrosilylation

SR Tamang, M Findlater - Molecules, 2019 - mdpi.com
Base metal catalysis offers an alternative to reactions, which were once dominated by
precious metals in hydrofunctionalization reactions. This review article details the …

Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes

M Magre, B Maity, A Falconnet… - Angewandte Chemie …, 2019 - Wiley Online Library
A magnesium‐catalyzed hydroboration of alkynes providing good yields and selectivities for
a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been …

Aluminum-catalyzed selective hydroboration of nitriles and alkynes: a multifunctional catalyst

N Sarkar, S Bera, S Nembenna - The Journal of Organic …, 2020 - ACS Publications
The reaction of LH [L={(ArNH)(ArN)–C= N–C=(NAr)(NHAr)}; Ar= 2, 6-Et2-C6H3] with a
commercially available alane amine adduct (H3Al· NMe2Et) in toluene resulted in the …

Low-Coordinate NHC–Zinc Hydride Complexes Catalyze Alkyne C–H Borylation and Hydroboration Using Pinacolborane

RJ Procter, M Uzelac, J Cid, PJ Rushworth… - ACS …, 2019 - ACS Publications
Organozinc compounds containing sp, sp2, and sp3 C–Zn moieties undergo transmetalation
with pinacolborane (HBPin) to produce Zn–H species and organoboronate esters (RBPin) …

Applications of catalysis in hydroboration of imines, nitriles, and carbodiimides

AR Bazkiaei, M Findlater, AEV Gorden - Organic & Biomolecular …, 2022 - pubs.rsc.org
The catalytic hydroboration of imines, nitriles, and carbodiimides is a powerful method of
preparing amines which are key synthetic intermediates in the synthesis of many value …