First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts
MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
Hydride transfer reactions catalyzed by cobalt complexes
W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …
characteristics and outstanding catalytic performance in addition to being cheap and earth …
Overview of regioselective and stereoselective catalytic hydroboration of alkynes
Hydroboration of alkynes is of special interest to researchers since it is the most
straightforward process for the synthesis of highly important vinylborane synthetic …
straightforward process for the synthesis of highly important vinylborane synthetic …
Alkenyl boronates: synthesis and applications
J Carreras, A Caballero… - Chemistry–An Asian …, 2019 - Wiley Online Library
Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …
synthesis owing to their accessible and efficient conversion into many different functional …
Emergence and applications of base metals (Fe, Co, and Ni) in hydroboration and hydrosilylation
SR Tamang, M Findlater - Molecules, 2019 - mdpi.com
Base metal catalysis offers an alternative to reactions, which were once dominated by
precious metals in hydrofunctionalization reactions. This review article details the …
precious metals in hydrofunctionalization reactions. This review article details the …
Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes
A magnesium‐catalyzed hydroboration of alkynes providing good yields and selectivities for
a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been …
a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been …
Aluminum-catalyzed selective hydroboration of nitriles and alkynes: a multifunctional catalyst
N Sarkar, S Bera, S Nembenna - The Journal of Organic …, 2020 - ACS Publications
The reaction of LH [L={(ArNH)(ArN)–C= N–C=(NAr)(NHAr)}; Ar= 2, 6-Et2-C6H3] with a
commercially available alane amine adduct (H3Al· NMe2Et) in toluene resulted in the …
commercially available alane amine adduct (H3Al· NMe2Et) in toluene resulted in the …
Low-Coordinate NHC–Zinc Hydride Complexes Catalyze Alkyne C–H Borylation and Hydroboration Using Pinacolborane
RJ Procter, M Uzelac, J Cid, PJ Rushworth… - ACS …, 2019 - ACS Publications
Organozinc compounds containing sp, sp2, and sp3 C–Zn moieties undergo transmetalation
with pinacolborane (HBPin) to produce Zn–H species and organoboronate esters (RBPin) …
with pinacolborane (HBPin) to produce Zn–H species and organoboronate esters (RBPin) …
Applications of catalysis in hydroboration of imines, nitriles, and carbodiimides
The catalytic hydroboration of imines, nitriles, and carbodiimides is a powerful method of
preparing amines which are key synthetic intermediates in the synthesis of many value …
preparing amines which are key synthetic intermediates in the synthesis of many value …