Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Light in gold catalysis

S Witzel, ASK Hashmi, J Xie - Chemical Reviews, 2021 - ACS Publications
Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …

Homogeneous and heterogeneous gold catalysis for materials science

CM Hendrich, K Sekine, T Koshikawa… - Chemical …, 2020 - ACS Publications
Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …

Merging photoinduced iron-catalyzed decarboxylation with copper catalysis for C–N and C–C couplings

N Xiong, Y Li, R Zeng - ACS Catalysis, 2023 - ACS Publications
We report a photoinduced iron/copper dual-catalytic strategy for the radical decarboxylation
functionalization of aliphatic carboxylic acids. The photoinduced ligand-to-iron charge …

Dinuclear gold catalysis

W Wang, CL Ji, K Liu, CG Zhao, W Li… - Chemical Society Reviews, 2021 - pubs.rsc.org
Gold chemistry has developed extensively in the past decade, and a dozen good reviews
have been presented discussing this progress. Few however have paid close attention to …

Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis

Y Ning, S Wang, M Li, J Han, C Zhu, J Xie - Nature Communications, 2021 - nature.com
Abstract Development of catalytic amide bond-forming methods is important because they
could potentially address the existing limitations of classical methods using …

Radical-mediated strategies for the functionalization of alkenes with diazo Compounds

YL Su, GX Liu, JW Liu, L Tram, H Qiu… - Journal of the American …, 2020 - ACS Publications
One of the most common reactions of diazo compounds with alkenes is cyclopropanation,
which occurs through metal carbene or free carbene intermediates. Alternative …

Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

HM Guo, X Wu - Nature Communications, 2021 - nature.com
The delivery of alkyl radicals through photocatalytic deoxygenation of primary alcohols
under mild conditions is a so far unmet challenge. In this report, we present a one-pot …

Phosphoranyl radical fragmentation reactions driven by photoredox catalysis

JA Rossi-Ashton, AK Clarke, WP Unsworth… - ACS …, 2020 - ACS Publications
Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method
for the generation of diverse and valuable radicals, typically via deoxygenation or …

Dinuclear gold (i) complexes: from bonding to applications

TACA Bayrakdar, T Scattolin, X Ma… - Chemical Society …, 2020 - pubs.rsc.org
The last two decades have seen a veritable explosion in the use of gold (I) complexes
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …