Visible light-induced transition metal catalysis
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …
Light in gold catalysis
S Witzel, ASK Hashmi, J Xie - Chemical Reviews, 2021 - ACS Publications
Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …
Homogeneous and heterogeneous gold catalysis for materials science
CM Hendrich, K Sekine, T Koshikawa… - Chemical …, 2020 - ACS Publications
Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …
used as a support. This review discusses the contributions of gold catalysis, both …
Merging photoinduced iron-catalyzed decarboxylation with copper catalysis for C–N and C–C couplings
N Xiong, Y Li, R Zeng - ACS Catalysis, 2023 - ACS Publications
We report a photoinduced iron/copper dual-catalytic strategy for the radical decarboxylation
functionalization of aliphatic carboxylic acids. The photoinduced ligand-to-iron charge …
functionalization of aliphatic carboxylic acids. The photoinduced ligand-to-iron charge …
Dinuclear gold catalysis
W Wang, CL Ji, K Liu, CG Zhao, W Li… - Chemical Society Reviews, 2021 - pubs.rsc.org
Gold chemistry has developed extensively in the past decade, and a dozen good reviews
have been presented discussing this progress. Few however have paid close attention to …
have been presented discussing this progress. Few however have paid close attention to …
Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis
Y Ning, S Wang, M Li, J Han, C Zhu, J Xie - Nature Communications, 2021 - nature.com
Abstract Development of catalytic amide bond-forming methods is important because they
could potentially address the existing limitations of classical methods using …
could potentially address the existing limitations of classical methods using …
Radical-mediated strategies for the functionalization of alkenes with diazo Compounds
YL Su, GX Liu, JW Liu, L Tram, H Qiu… - Journal of the American …, 2020 - ACS Publications
One of the most common reactions of diazo compounds with alkenes is cyclopropanation,
which occurs through metal carbene or free carbene intermediates. Alternative …
which occurs through metal carbene or free carbene intermediates. Alternative …
Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
HM Guo, X Wu - Nature Communications, 2021 - nature.com
The delivery of alkyl radicals through photocatalytic deoxygenation of primary alcohols
under mild conditions is a so far unmet challenge. In this report, we present a one-pot …
under mild conditions is a so far unmet challenge. In this report, we present a one-pot …
Phosphoranyl radical fragmentation reactions driven by photoredox catalysis
Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method
for the generation of diverse and valuable radicals, typically via deoxygenation or …
for the generation of diverse and valuable radicals, typically via deoxygenation or …
Dinuclear gold (i) complexes: from bonding to applications
TACA Bayrakdar, T Scattolin, X Ma… - Chemical Society …, 2020 - pubs.rsc.org
The last two decades have seen a veritable explosion in the use of gold (I) complexes
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …