Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

This review describes the recent advances in understanding of the mechanism of palladium
catalyzed C–C cross-coupling reactions. The discussion is focused on the role of palladium …

Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the
system of choice for homogeneous catalysis with well-defined molecular active species due …

Mesoionic carbenes have found wide use as components of homogeneous catalysts.
Recent discoveries have, however, shown that metal complexes of such ligands also have …

Pyridine-appended triazolylidene donors have been recently used as ligands in various
homogeneous catalytic processes. We present here a new pyrimidine substituted triazolium …

We report the synthesis of vanadium (V) oxo complex 1 with a pincer-type dianionic
mesoionic carbene (MIC) ligand L 1 and the general formula [VOCl (L1)]. A comparison of …

Bimetallic complexes bearing NHC donor ligands are gaining immense popularity as
catalysts in organometallic chemistry. However, such complexes with a mixed NHC/PR3 …

With the goal of achieving highly efficient palladium-catalyzed cross-coupling reactions
under mild reaction conditions, the Pd-PEPPSI complexes C1 and C2 bearing 1, 2-di (tert …

The field of asymmetric catalysis is rapidly developing and the chiral ligands play a key role
in enantioselective transition‐metal catalysis. The electron‐rich chiral N‐heterocyclic …

Triazolylidenes are a prominent class of mesoionic carbenes that have found use as
supporting ligands in homogeneous catalysis in recent years. We present here the …