[HTML][HTML] Strategies to improve the catalytic activity and stability of bioinspired Cu molecular catalysts for the ORR
The oxygen reduction reaction (ORR) is essential for energy conversion devices such as
fuel cells and metal-air batteries. The use of expensive and scarce noble metal materials to …
fuel cells and metal-air batteries. The use of expensive and scarce noble metal materials to …
Recent advances of Fe–N–C pyrolyzed catalysts for the oxygen reduction reaction
K Muñoz-Becerra, R Venegas, L Duque… - Current Opinion in …, 2020 - Elsevier
This review summarizes recent advances in the development of pyrolyzed M–N–C catalysts
for the oxygen reduction reaction, focusing on activity, stability, and the reactivity descriptors …
for the oxygen reduction reaction, focusing on activity, stability, and the reactivity descriptors …
Experimental reactivity descriptors of MNC catalysts for the oxygen reduction reaction
Pyrolyzed non-precious metal catalysts (NPMCs) are promising materials to replace
platinum-based catalysts in the cathode of the fuel cells. These catalysts present high …
platinum-based catalysts in the cathode of the fuel cells. These catalysts present high …
Charge-Transfer Spectroscopy of Bisaxially Coordinated Iron(II) Phthalocyanines through the Prism of the Lever's EL Parameters Scale, MCD Spectroscopy, and …
DE Nevonen, LS Ferch, BR Schrage… - Inorganic …, 2022 - ACS Publications
The position of the experimentally observed (in the UV–vis and magnetic circular dichroism
(MCD) spectra) low-energy metal-to-ligand charge-transfer (MLCT) band in low-spin iron (II) …
(MCD) spectra) low-energy metal-to-ligand charge-transfer (MLCT) band in low-spin iron (II) …
[HTML][HTML] Proving ligand structure-reactivity correlation on multinuclear copper electrocatalysts supported on carbon black for the oxygen reduction reaction
R Venegas, K Muñoz-Becerra, S Juillard, L Zhang… - Electrochimica …, 2022 - Elsevier
Bioinspired transition-metal catalysts seek to mimic the specific active site of
metalloenzymes, as the multicopper oxidase, that can efficiently reduce dioxygen to water …
metalloenzymes, as the multicopper oxidase, that can efficiently reduce dioxygen to water …
Accurate Prediction of Mössbauer Hyperfine Parameters in Bis-Axially Coordinated Iron (II) Phthalocyanines Using Density Functional Theory Calculations: A Story …
VN Nemykin, DE Nevonen, LS Ferch, M Shepit… - Inorganic …, 2021 - ACS Publications
Density Functional Theory (DFT) calculations coupled with several exchange-correlation
functionals were used for the prediction of Mössbauer hyperfine parameters of 36 bis …
functionals were used for the prediction of Mössbauer hyperfine parameters of 36 bis …
A novel oxidation-reduction method for highly selective detection of cysteine over reduced glutathione based on synergistic effect of fully fluorinated cobalt …
B Yuan, H Wang, J Cai, Y Peng, Y Niu, H Chen… - Sensors and Actuators B …, 2019 - Elsevier
Abstract l-Cysteine (Cys) and reduced glutathione (GSH) are important biothiols which are
indicators of diseases risk and health status. However, it is difficult to discriminate them due …
indicators of diseases risk and health status. However, it is difficult to discriminate them due …
Application of Lever's EL Parameter Scale toward Fe(II)/Fe(III) versus Pc(2-)/Pc(1-) Oxidation Process Crossover Point in Axially Coordinated Iron(II) Phthalocyanine …
VN Nemykin, DE Nevonen, WR Osterloh… - Inorganic …, 2021 - ACS Publications
The electronic structures and, particularly, the nature of the HOMO in a series of PcFeL2,
PcFeL′ L ″, and [PcFeX2] 2–complexes (Pc= phthalocyaninato (2-) ligand; L= NH3, n …
PcFeL′ L ″, and [PcFeX2] 2–complexes (Pc= phthalocyaninato (2-) ligand; L= NH3, n …
Resolving a Half-Century-Long Controversy between (Magneto)optical and EPR Spectra of Single-Electron-Reduced [PcFe]−, [PcFeL]−, and [PcFeX]2– Complexes …
BR Schrage, W Zhou, LA Harrison… - Inorganic …, 2022 - ACS Publications
The reduction of iron (II) phthalocyanine (Pc (2−) FeII) or its bisaxially coordinated
complexes results in the formation of the purple/red [PcFe]−,[PcFeL]−, and [PcFeX] 2–(L is …
complexes results in the formation of the purple/red [PcFe]−,[PcFeL]−, and [PcFeX] 2–(L is …
The Redox‐Active Chromium Phthalocyanine System: Isolation of Five Oxidation States from Pc4−CrI to Pc2−CrIII
W Zhou, JR Thompson, CC Leznoff… - … –A European Journal, 2017 - Wiley Online Library
The preparation and structural characterization of a series of chromium phthalocyanine
complexes with multiple metal and ring oxidation states were achieved using PcCrII (1)(Pc …
complexes with multiple metal and ring oxidation states were achieved using PcCrII (1)(Pc …