Late-stage C–H functionalization of azines
CM Josephitis, HMH Nguyen, A McNally - Chemical reviews, 2023 - ACS Publications
Azines, such as pyridines, quinolines, pyrimidines, and pyridazines, are widespread
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …
Visible-light-induced organophotoredox-catalyzed difunctionalization of alkenes and alkynes
In the era of organic synthesis, the direct difunctionalization strategies of alkenes and
alkynes are very eminent, which open up an excellent route to introduce two functional …
alkynes are very eminent, which open up an excellent route to introduce two functional …
Photodecarboxylative C–H Alkylation of Azauracils with N-(Acyloxy)phthalimides
We disclose a transition-metal-free NaI/PPh3-mediated direct C–H alkylation of azauracils
using N-(acyloxy) pthalimides (NHPIs) as readily available alkyl surrogates under visible …
using N-(acyloxy) pthalimides (NHPIs) as readily available alkyl surrogates under visible …
A General Electron Donor–Acceptor Photoactivation Platform of Diaryliodonium Reagents: Arylation of Heterocycles
We report a photoredox system comprising sodium iodide, triphenyl phosphine, and N, N,
N′, N′-tetramethylethylenediamine (TMEDA) that can form a self-assembled tetrameric …
N′, N′-tetramethylethylenediamine (TMEDA) that can form a self-assembled tetrameric …
Organophotoredox-Catalyzed Arylation and Aryl Sulfonylation of Morita–Baylis–Hillman Acetates with Diaryliodonium Reagents
S Senapati, SK Parida, SS Karandikar… - Organic Letters, 2023 - ACS Publications
We report an organophotoredox-catalyzed stereoselective allylic arylation of MBH acetates
with a palette of diaryliodonium triflates (DAIRs) to provide the corresponding trisubstituted …
with a palette of diaryliodonium triflates (DAIRs) to provide the corresponding trisubstituted …
Visible Light Photoredox-Catalyzed Direct C–H Arylation of Quinoxalin-2(1H)-ones with Diaryliodonium Salts
A photoredox-catalyzed direct arylation of quinoxalin-2-(1 H)-ones using diaryliodonium
triflates as the convenient, stable, and cheap aryl source is described. A broad variety of …
triflates as the convenient, stable, and cheap aryl source is described. A broad variety of …
Visible-light-induced metal-free coupling of C (sp 3)–H sources with heteroarenes
Development of an efficient, mild, economically viable, and green method for the
construction of a Csp2–Csp3 bond via coupling between a saturated hydrocarbon [(Csp3) …
construction of a Csp2–Csp3 bond via coupling between a saturated hydrocarbon [(Csp3) …
Photocatalytic Alkylation/Arylative Cyclization of N-Acrylamides of N-Heteroarenes and Arylamines with Dihydroquinazolinones from Unactivated Ketones
S Bag, S Ojha, S Venugopalan… - The Journal of Organic …, 2023 - ACS Publications
We describe a visible-light photoredox-catalyzed alkylation/arylative cyclization of N-
acrylamides─ from 2-arylindoles, 2-arylbenzimidazoles, or N-substituted anilines─ with …
acrylamides─ from 2-arylindoles, 2-arylbenzimidazoles, or N-substituted anilines─ with …
Visible-light-induced cascade reaction: a sustainable approach towards molecular complexity
Photoredox catalysis has demonstrated rapid evolution in the field of synthetic organic
chemistry. On the other hand, the splendour of cascade reactions in providing complex …
chemistry. On the other hand, the splendour of cascade reactions in providing complex …
Visible light-induced functionalization of indazole and pyrazole: a recent update
Indazole and pyrazole are renowned as a prodigious class of heterocycles having versatile
uses in medicinal as well as industrial chemistry. Considering sustainable approaches …
uses in medicinal as well as industrial chemistry. Considering sustainable approaches …