Base metal chemistry and catalysis
ML Clapson, CS Durfy, D Facchinato… - Cell Reports Physical …, 2023 - cell.com
This perspective provides an entry-level conversation concerning base metal catalysis as a
green and sustainable solution in industrial and academic contexts. We establish a …
green and sustainable solution in industrial and academic contexts. We establish a …
Amine-functionalized polybutadiene synthesis by tunable postpolymerization hydroaminoalkylation
Early transition metal-catalyzed hydroaminoalkylation is a powerful single-step method to
selectively add amines to polybutadienes, offering an efficient strategy to access amine …
selectively add amines to polybutadienes, offering an efficient strategy to access amine …
Recent Advances in Saturated N-Heterocycle C–H Bond Functionalization for Alkylated N-Heterocycle Synthesis
CHM Zheng, LL Schafer - Synthesis, 2024 - thieme-connect.com
The prominence of saturated N-heterocycle motifs in pharmaceuticals is undeniable.
Challenges associated with the alkylation of saturated N-heterocycle scaffolds to efficiently …
Challenges associated with the alkylation of saturated N-heterocycle scaffolds to efficiently …
Methyl Methacrylate Production Processes: A Comparative Analysis of Alternatives Using the Life Cycle Assessment Methodology
AA Adeoye, F Passarini, J De Maron… - ACS Sustainable …, 2023 - ACS Publications
Green chemistry is part of the chemical industry's response to calls for improved
environmental responsibility. It is also one of the industry's several paths to redemption from …
environmental responsibility. It is also one of the industry's several paths to redemption from …
Hydroaminoalkylation for Amine Functionalization of Vinyl‐Terminated Polyethylene Enables Direct Access to Responsive Functional Materials
While functionalized polyethylenes (PEs) exhibit valuable characteristics, the constraints of
existing synthetic approaches limit the variety of readily incorporated functionality. New …
existing synthetic approaches limit the variety of readily incorporated functionality. New …
Exploiting natural complexity for substrate controlled regioselectivity and stereoselectivity in tantalum catalysed hydroaminoalkylation
CHM Zheng, BE Nadeau, HL Trajano, LL Schafer - Green Chemistry, 2024 - pubs.rsc.org
Naturally occurring and structurally diverse alkene-containing substrates, terpenes, provided
a platform for establishing chemo-, regio-, and diastereoselective reactivity in tantalum …
a platform for establishing chemo-, regio-, and diastereoselective reactivity in tantalum …
Tantalum Catalyzed Hydroaminoalkylation Enables a Telescoping Catalytic Reaction Sequence for the Synthesis of Benzoannulated Indolizidines and Quinolizidines
CHM Zheng, CA Esslinger, OF Dressler… - …, 2024 - ACS Publications
The synthesis of benzoannulated indolizidines and quinolizidines is described through a
telescoping reaction sequence featuring hydroaminoalkylation and nickel-catalyzed C–N …
telescoping reaction sequence featuring hydroaminoalkylation and nickel-catalyzed C–N …
Mechanochemical Synthesis of Chromium (III) Complexes Containing Bidentate PN and Tridentate P-NH-P and P-NH-P′ Ligands
Chromium (III) complexes bearing bidentate {NH2 (CH2) 2PPh2: PN,(S, S)-[NH2 (CHPh)
2PPh2]: P'N} and tridentate [Ph2P (CH2) 2N (H)(CH2) 2PPh2: P-NH-P,(S, S)-(i Pr) …
2PPh2]: P'N} and tridentate [Ph2P (CH2) 2N (H)(CH2) 2PPh2: P-NH-P,(S, S)-(i Pr) …
Catalytic Installation of Primary Amines Onto Polyolefins for Oligomer Valorization
Polymerization of primary amine‐containing monomers is challenging because the amine
inhibits polymerization catalyst activity. An alternative approach to access primary amine …
inhibits polymerization catalyst activity. An alternative approach to access primary amine …