Manipulating metal atoms in a controllable way for the synthesis of materials with the
desired structure and properties is the holy grail of chemical synthesis. The recent …

The array of transition-metal-catalyzed cross-coupling reactions can easily be considered
nowadays cornerstones in the field of organic synthesis. 1, 2 Among them, the palladium …

We have demonstrated a methodology to generate large area graphdiyne films with 3.61
cm2 on the surface of copper via a cross-coupling reaction using hexaethynylbenzene. The …

Using density functional theory coupled with Boltzmann transport equation with relaxation
time approximation, we investigate the electronic structure and predict the charge mobility …

Graphdiyne, a sp-and sp2-hybridized 2D π-conjugated carbon material with well-dispersed
pores and unique electronic properties, was well investigated and applied in catalysis …

One of the most important objectives in materials, chemical, and physical sciences is the
creation of large conjugated macrocycles with well‐defined shapes, since such molecules …

In light of the considerable impact synthetic 2D polymers are expected to have on many
fundamental and applied aspects of the natural and engineering sciences, it is surprising …

New carbon materials have recently been derived from graphene theoretically and
experimentally, hydrogenated graphene (graphane), fluorinated graphene (fluorographene) …

We report the electronic structure and optical properties of the recently synthesized stable
two-dimensional carbon allotrope graphdiyne based on first-principles calculations and …

Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …