Recent progress in heterogeneous metal and metal oxide catalysts for direct dehydrogenation of ethane and propane

Y Dai, X Gao, Q Wang, X Wan, C Zhou… - Chemical Society …, 2021 - pubs.rsc.org
Catalytic non-oxidative direct dehydrogenation of light alkanes serves as an effective
reinforcement to selectively produce the corresponding olefins, and the heterogeneous …

Single-atom alloy catalysts: structural analysis, electronic properties and catalytic activities

T Zhang, AG Walsh, J Yu, P Zhang - Chemical Society Reviews, 2021 - pubs.rsc.org
Monometallic catalysts, in particular those containing noble metals, are frequently used in
heterogeneous catalysis, but they are expensive, rare and the ability to tailor their structures …

Stable and selective catalysts for propane dehydrogenation operating at thermodynamic limit

AH Motagamwala, R Almallahi, J Wortman… - Science, 2021 - science.org
Intentional (“on-purpose”) propylene production through nonoxidative propane
dehydrogenation (PDH) holds great promise for meeting the increasing global demand for …

First-principles design of a single-atom–alloy propane dehydrogenation catalyst

RT Hannagan, G Giannakakis, R Réocreux… - Science, 2021 - science.org
The complexity of heterogeneous catalysts means that a priori design of new catalytic
materials is difficult, but the well-defined nature of single-atom–alloy catalysts has made it …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

Propane to olefins tandem catalysis: a selective route towards light olefins production

M Monai, M Gambino, S Wannakao… - Chemical Society …, 2021 - pubs.rsc.org
On-purpose synthetic routes for propylene production have emerged in the last couple of
decades in response to the increasing demand for plastics and a shift to shale gas …

Design strategies of stable catalysts for propane dehydrogenation to propylene

ML Sun, ZP Hu, HY Wang, YJ Suo, ZY Yuan - ACS Catalysis, 2023 - ACS Publications
Propylene is one of the most important building blocks for the chemical industry. Traditional
propylene production, which is based on oil-based cracking processes, is being challenged …

C–H bond activation in light alkanes: a theoretical perspective

Y Wang, P Hu, J Yang, YA Zhu, D Chen - Chemical Society Reviews, 2021 - pubs.rsc.org
Alkanes are the major constituents of natural gas and crude oil, the feedstocks for the
chemical industry. The efficient and selective activation of C–H bonds can convert abundant …

Size dependence of Pt catalysts for propane dehydrogenation: from atomically dispersed to nanoparticles

W Zhang, H Wang, J Jiang, Z Sui, Y Zhu, D Chen… - ACS …, 2020 - ACS Publications
The structure–performance relationship is a critical fundamental issue in heterogeneous
catalysis, and the size-dependent structure sensitivity of catalytic reactions has long been …

Carbon deposit analysis in catalyst deactivation, regeneration, and rejuvenation

ETC Vogt, D Fu, BM Weckhuysen - … Chemie International Edition, 2023 - Wiley Online Library
Hydrocarbon conversion catalysts suffer from deactivation by deposition or formation of
carbon deposits. Carbon deposit formation is thermodynamically favored above 350° C …