Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Metal-catalyzed carbon–carbon bond cleavage of unstrained alcohols

MDR Lutz, B Morandi - Chemical reviews, 2020 - ACS Publications
The functionalization of molecules by cleaving inert carbon–carbon single bonds is
regarded as a great synthetic challenge due to their inherent stability. In recent years …

Catalytic activations of unstrained C–C bond involving organometallic intermediates

F Song, T Gou, BQ Wang, ZJ Shi - Chemical Society Reviews, 2018 - pubs.rsc.org
The cleavage of C–C bonds has been a great challenge owing to their thermodynamic and
kinetic stability. To date, the progress made in this area has mainly relied on the reaction of …

Asymmetric hydrogenation of heteroarenes and arenes

DS Wang, QA Chen, SM Lu, YG Zhou - Chemical reviews, 2012 - ACS Publications
The range of application of organic compounds is enormous due to that organic compounds
are structurally diverse. They either form the basis of or are important constituents of many …

Recent advances in transition-metal-catalyzed functionalization of unstrained carbon–carbon bonds

F Chen, T Wang, N Jiao - Chemical Reviews, 2014 - ACS Publications
The carbon− carbon bond is the most widespread and fundamental bond existing in organic
compounds. The reaction of this kind of bond is almost ubiquitous in live activities and …

Direct functionalization processes: A journey from palladium to copper to iron to nickel to metal-free coupling reactions

JJ Mousseau, AB Charette - Accounts of Chemical Research, 2013 - ACS Publications
The possibility of finding novel disconnections for the efficient synthesis of organic
molecules has driven the interest in developing technologies to directly functionalize C–H …

Nickel‐and photoredox‐catalyzed cross‐coupling reactions of aryl halides with 4‐Alkyl‐1, 4‐dihydropyridines as formal nucleophilic alkylation reagents

K Nakajima, S Nojima, Y Nishibayashi - Angewandte Chemie, 2016 - Wiley Online Library
A combination of nickel and photoredox catalysts promoted novel cross‐coupling reactions
of aryl halides with 4‐alkyl‐1, 4‐dihydropyridines. 4‐Alkyl‐1, 4‐dihydropyridines act as …

Pyridinyl directed alkenylation with olefins via Rh (iii)-catalyzed C–C bond cleavage of secondary arylmethanols

H Li, Y Li, XS Zhang, K Chen, X Wang… - Journal of the American …, 2011 - ACS Publications
Novel C–C bond cleavage of secondary alcohols through Rh (III)-catalyzed β-carbon
elimination directed by a pyridinyl group is reported. A five-membered rhodacycle is …

Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes to N-Sulfonyl Aldimines via C−H Bond Activation

B Qian, S Guo, J Shao, Q Zhu, L Yang… - Journal of the …, 2010 - ACS Publications
An efficient protocol for the generation of amines by palladium-catalyzed nucleophilic
benzylic addition of 2-methyl-substituted azaarenes to N-sulfonyl aldimines under neutral …

Palladium-catalyzed decarboxylative couplings of 2-(2-azaaryl) acetates with aryl halides and triflates

R Shang, ZW Yang, Y Wang, SL Zhang… - Journal of the American …, 2010 - ACS Publications
Pd-catalyzed decarboxylative cross-couplings of 2-(2-azaaryl) acetates with aryl halides and
triflates have been discovered. This reaction is potentially useful for the synthesis of some …