Polyhedral oligomeric silsesquioxane (POSS)‐hybrid polymers have been successfully
employed as functional inorganic–organic hybrid materials for various applications due to …

Cage-like silsesquioxanes are considered to be ideal and versatile building blocks of hybrid
materials due to their unique structures and excellent performance. This Perspective …

Shape amphiphiles refer to a class of molecular conjugates composed by distinct building
blocks with incommensurate shapes and chemical interactions. Whilst extensive efforts have …

Polymeric chains made of “giant” monomers at a larger length scale provide intriguing
insights into the fundamental principles of polymer science. In this study, we modularly …

The vastly expanding chemical and architectural parameter space of multiblock copolymers
brings both opportunities and challenges for tailoring the structure and properties of a …

Macromolecular isomerism has been an important yet largely understudied subject. Giant
molecules based on molecular nanoparticles exhibit properties highly dependent on the …

The performance of 2D nanomaterials hinges on both the chemical compositions and the
morphological structures across different length scales. Among all the three dimensions …

Anisotropic patchy particles with molecular precision are exquisite building blocks for
constructing diverse meso-structures of high complexity. In this research, a library of …

Branched architecture profoundly influences the physical properties of polymers, making it
an important topic in the field of polymer science. Herein, we report a facile synthetic strategy …

The pursuit of precision in polymer synthesis and assembly has been the Holy Grail of
macromolecular science. Nowadays, precision macromolecules have come to the interface …