Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Recent advances in hydrodeoxygenation of biomass-derived oxygenates over heterogeneous catalysts

S Kim, EE Kwon, YT Kim, S Jung, HJ Kim… - Green …, 2019 - pubs.rsc.org
Hydrodeoxygenation (HDO) using heterogeneous catalysts has received considerable
attention as a way of converting biomass-derived oxygenates into renewable fuels and …

Promoting exsolution of RuFe alloy nanoparticles on Sr2Fe1.4Ru0.1Mo0.5O6−δ via repeated redox manipulations for CO2 electrolysis

H Lv, L Lin, X Zhang, R Li, Y Song… - Nature …, 2021 - nature.com
Metal nanoparticles anchored on perovskite through in situ exsolution under reducing
atmosphere provide catalytically active metal/oxide interfaces for CO2 electrolysis in solid …

Opportunities and challenges in the development of advanced materials for emission control catalysts

AK Datye, M Votsmeier - Nature Materials, 2021 - nature.com
Advances in engine technologies are placing additional demands on emission control
catalysts, which must now perform at lower temperatures, but at the same time be robust …

Nanoparticle ex-solution for supported catalysts: materials design, mechanism and future perspectives

JH Kim, JK Kim, J Liu, A Curcio, JS Jang, ID Kim… - ACS …, 2020 - ACS Publications
Supported metal catalysts represent one of the major milestones in heterogeneous catalysis.
Such catalytic systems are feasible for use in a broad range of applications, including …

Modulating the dynamics of Brønsted acid sites on PtWOx inverse catalyst

J Fu, S Liu, W Zheng, R Huang, C Wang, A Lawal… - Nature Catalysis, 2022 - nature.com
Brønsted acid sites on the oxide overlayers of metal–metal oxide inverse catalysts are often
hypothesized to drive selective C–O bond activation. However, the Brønsted acid site nature …

Perovskites as geo-inspired oxygen storage materials for chemical looping and three-way catalysis: a perspective

X Zhu, K Li, L Neal, F Li - Acs Catalysis, 2018 - ACS Publications
With highly tunable composition, structure, and chemical-physical properties, perovskite
oxides represent a large family of mixed-oxide materials that finds many energy-and …

Highly active dry methane reforming catalysts with boosted in situ grown Ni-Fe nanoparticles on perovskite via atomic layer deposition

S Joo, A Seong, O Kwon, K Kim, JH Lee, RJ Gorte… - Science …, 2020 - science.org
With the need for more stable and active metal catalysts for dry reforming of methane, in situ
grown nanoparticles using exsolution are a promising approach. However, in conventional …

Encapsulation methods for control of catalyst deactivation: a review

HO Otor, JB Steiner, C Garcia-Sancho… - ACS …, 2020 - ACS Publications
One of the most significant challenges in the use of heterogeneous catalysts is the loss of
activity and/or selectivity with time on stream, and researchers have explored different …

A Hydrothermally Stable Irreducible Oxide‐Modified Pd/MgAl2O4 Catalyst for Methane Combustion

J Yang, M Peng, G Ren, H Qi, X Zhou, J Xu… - Angewandte …, 2020 - Wiley Online Library
Catalytic combustion is promising in removing trace amounts of CH4 to address serious
environmental concerns. Supported Pd‐based catalysts are most effective but often suffer …