Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Weak-coordination in C–H bond functionalizations catalyzed by 3d metals

R Mandal, B Garai, B Sundararaju - ACS Catalysis, 2022 - ACS Publications
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …

(Pentamethylcyclopentadienyl) cobalt (III)‐Catalyzed C–H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity

T Yoshino, S Matsunaga - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Abstract High‐valent (pentamethylcyclopentadienyl) cobalt (III)[Cp* Co (III)] catalysts were
found as inexpensive alternatives to (pentamethylcyclopentadienyl) rhodium (III)[Cp* Rh (III)] …

Recent advances in chelation-assisted site-and stereoselective alkenyl C–H functionalization

J Zhang, X Lu, C Shen, L Xu, L Ding… - Chemical Society …, 2021 - pubs.rsc.org
Olefinic C–H functionalization represents an atom-and step economic approach to valuable
olefin derivatives from simpler ones, but controlling the selectivity remains a challenge …

Recent advances in transition metal-catalyzed olefinic C–H functionalization

B Liu, L Yang, P Li, F Wang, X Li - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal-catalyzed directed C–H activation has emerged as an increasingly powerful
tool for the synthesis of important organic building blocks, organic materials and natural …

Cobalt (II)-catalyzed electrooxidative C–H amination of arenes with alkylamines

X Gao, P Wang, L Zeng, S Tang… - Journal of the American …, 2018 - ACS Publications
An environmentally friendly electrochemical protocol about cobalt-catalyzed C–H amination
of arenes has been developed, which offers a simple way to access synthetically useful …

C–H functionalization by high-valent Cp* Co (III) catalysis

S Wang, SY Chen, XQ Yu - Chemical Communications, 2017 - pubs.rsc.org
Significant progress has been accomplished in directed C–H functionalization through the
use of earth-abundant and inexpensive first-row transition metals. Among these base …

Direct functionalization of C− H bonds by iron, nickel, and cobalt catalysis

G Pototschnig, N Maulide… - Chemistry–A European …, 2017 - Wiley Online Library
Non‐precious‐metal‐catalyzed reactions are of increasing importance in chemistry due to
the outstanding ecological and economic properties of these metals. In the subfield of metal …