Toolbox for distal C–H bond functionalizations in organic molecules

SK Sinha, S Guin, S Maiti, JP Biswas, S Porey… - Chemical …, 2021 - ACS Publications
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

[HTML][HTML] Metal-catalysed C–H bond activation and borylation

R Bisht, C Haldar, MMM Hassan, ME Hoque… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Transition metal–catalyzed remote C─ H borylation: An emerging synthetic tool

MMM Hassan, S Guria, S Dey, J Das… - Science …, 2023 - science.org
Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

Arene diversification through distal C(sp2)−H functionalization

U Dutta, S Maiti, T Bhattacharya, D Maiti - Science, 2021 - science.org
BACKGROUND Organic synthetic chemistry has facilitated the production of medicines,
agrochemicals, food, polymers, dyes, and more through step-and atom-economical …

Transition metal-catalyzed site-and regio-divergent C–H bond functionalization

L Ping, DS Chung, J Bouffard, S Lee - Chemical Society Reviews, 2017 - pubs.rsc.org
Recent advances in transition metal-catalyzed C–H bond functionalization have profoundly
impacted synthetic strategy. Since organic substrates typically contain several chemically …

Remote steric control for undirected meta-selective C–H activation of arenes

B Ramadoss, Y Jin, S Asako, L Ilies - Science, 2022 - science.org
Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …

Remarkably Efficient Iridium Catalysts for Directed C(sp2)–H and C(sp3)–H Borylation of Diverse Classes of Substrates

ME Hoque, MMM Hassan… - Journal of the American …, 2021 - ACS Publications
Here we describe the discovery of a new class of C–H borylation catalysts and their use for
regioselective C–H borylation of aromatic, heteroaromatic, and aliphatic systems. The new …

Noncovalent interactions in metal complex catalysis

KT Mahmudov, AV Gurbanov, FI Guseinov… - Coordination Chemistry …, 2019 - Elsevier
Metal complex catalysis, in which coordination compounds are designed as catalysts for
chemical transformations employing noncovalent interactions, is emerging as a powerful …

Recent advances in catalytic C− H borylation reactions

L Xu, G Wang, S Zhang, H Wang, L Wang, L Liu, J Jiao… - Tetrahedron, 2017 - Elsevier
In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …