Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Strategies for enhancing the heterogeneous Fenton catalytic reactivity: A review

Y Zhu, R Zhu, Y Xi, J Zhu, G Zhu, H He - Applied Catalysis B …, 2019 - Elsevier
Heterogeneous Fenton reactions have gained widespread attention in removing recalcitrant
organic contaminants as the reaction between solid Fenton catalysts and H 2 O 2 can …

Critical review of reductant-enhanced peroxide activation processes: Trade-off between accelerated Fe3+/Fe2+ cycle and quenching reactions

H Zhou, H Zhang, Y He, B Huang, C Zhou… - Applied Catalysis B …, 2021 - Elsevier
In this review, we systematically summarized the origins, development, basic mechanism
and limits of reductant-enhanced iron-based peroxide activation processes (including H 2 O …

Enhancing iron redox cycling for promoting heterogeneous Fenton performance: A review

C Lai, X Shi, L Li, M Cheng, X Liu, S Liu, B Li… - Science of The Total …, 2021 - Elsevier
Conventional water treatment methods are difficult to remove stubborn pollutants emerging
from surface water. Advanced oxidation processes (AOPs) can achieve a higher level of …

Photo-aging of polyvinyl chloride microplastic in the presence of natural organic acids

C Wang, Z Xian, X Jin, S Liang, Z Chen, B Pan, B Wu… - Water Research, 2020 - Elsevier
In this study, a new photo-aging pathway in the aquatic environments and the underlying
transformation mechanism were described for polyvinyl chloride microplastic (PVC-MP). Our …

Room-temperature preparation of highly efficient NH2-MIL-101 (Fe) catalyst: The important role of–NH2 in accelerating Fe (III)/Fe (II) cycling

P Huang, L Yao, Q Chang, Y Sha, G Jiang, S Zhang… - Chemosphere, 2022 - Elsevier
The slow redox rate of Fe (III)/Fe (II) couples is a rate-limiting step for Fenton-like
performance of Fe-MOFs. In this study, a series of catalysts (MIL-101) with various p-phthalic …

Ascorbate tumor chemotherapy by an iron-engineered nanomedicine-catalyzed tumor-specific pro-oxidation

B Yang, J Shi - Journal of the American Chemical Society, 2020 - ACS Publications
Ascorbate, a kind of polyhydroxy compound with a long history, has been extensively
considered as an efficient antioxidant. However, only in the past several decades its pro …

Contaminant degradation by• OH during sediment oxygenation: dependence on Fe (II) species

W Xie, S Yuan, M Tong, S Ma, W Liao… - Environmental …, 2020 - ACS Publications
It has been documented that contaminants could be degraded by hydroxyl radicals (• OH)
produced upon oxygenation of Fe (II)-bearing sediments. However, the dependence of …

Generation of H2O2 by on-site activation of molecular dioxygen for environmental remediation applications: A review

L Pi, J Cai, L Xiong, J Cui, H Hua, D Tang… - Chemical Engineering …, 2020 - Elsevier
The unique characteristics of H 2 O 2 render it a versatile and green agent for environmental
remediation applications. As an essential component of a classic Fenton or Fenton-like …

Degradation of p-nitrophenol using a ferrous-tripolyphosphate complex in the presence of oxygen: The key role of superoxide radicals

C Zhang, T Li, J Zhang, S Yan, C Qin - Applied Catalysis B: Environmental, 2019 - Elsevier
It has been recognized that a ferrous–polyphosphate complex can activate oxygen to
produce reactive oxygen species (ROS) capable of degrading organic compounds. radical …