BACKGROUND The concept of immiscibility of certain liquids, such as oil and water, must
have been known to the humankind for millennia, and it must have captivated early …

Charge transfer phenomena at the interface between two immiscible electrolyte solutions
(ITIES) are electrochemical reactions taking place in soft media. Owing to their liquid nature …

Mean field theories of ion distributions, such as the Gouy-Chapman theory that describes the
distribution near a charged planar surface, ignore the molecular-scale structure in the liquid …

Provides a comprehensive treatment of surface chemistry and its applications to chemical
engineering, biology, and medicine. Focuses on the chmical and physical structure of oil …

The distribution of electrolytes in an electric field usually relies on theories based on the
Poisson–Boltzmann formalism. These models predict that, in the case of a metallic …

We present a theoretical comparison of the surface forces between two graphite-like
surfaces at salt concentrations below 10 mM with surfaces charged by various mechanisms …

The effect of potential bias on the wettability of graphite using immiscible electrolyte
solutions (ITIES) is investigated. The mechanism of the phenomenon is elucidated by …

Abstract Interpretation of electrochemical data generated at the interface between two
immiscible electrolyte solutions (ITIES), and realisation of the ITIES for technological …

Electrified interfaces continue to play a central role in condensed-phase physical chemistry.
The last couple of decades have seen enormous strides in our understanding of these …

Most researches on oil droplets immersed in aqueous solutions assume that the surface
charges of oil droplets are, similar to that of solid particles, immobile and distributed …