Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Chirality in adsorption on solid surfaces

F Zaera - Chemical Society Reviews, 2017 - pubs.rsc.org
In the present review we survey the main advances made in recent years on the
understanding of chemical chirality at solid surfaces. Chirality is an important topic, made …

Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces

S Dutta, AJ Gellman - Chemical Society Reviews, 2017 - pubs.rsc.org
Research on surface chirality is motivated by the need to develop functional chiral surfaces
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …

[HTML][HTML] Surface chemistry for enantioselective catalysis

AJ Gellman, WT Tysoe, F Zaera - Catalysis Letters, 2015 - Springer
A Perspective is offered on the lessons learned from surface-science studies on
enantioselective chemistry on solid surfaces performed by the author's groups. Our …

A Method for Obtaining Liquid–Solid Adsorption Rates from Molecular Dynamics Simulations: Applied to Methanol on Pt(111) in H2O

X Zhang, A Savara, RB Getman - Journal of chemical theory and …, 2020 - ACS Publications
Adsorption is an important step in heterogeneous catalysis as it predetermines how many
reactant molecules can participate in a surface reaction per unit time. While the rate of …

Use of molecular beams for kinetic measurements of chemical reactions on solid surfaces

F Zaera - Surface Science Reports, 2017 - Elsevier
In this review we survey the contributions that molecular beam experiments have provided to
our understanding of the dynamics and kinetics of chemical interactions of gas molecules …

Thermodynamics of Carbon Monoxide Adsorption on Cu/SBA-15 Catalysts: Under Vacuum versus under Atmospheric Pressures

T Han, I Lee, Y Cao, X Zhou… - The Journal of Physical …, 2022 - ACS Publications
The thermodynamics of the adsorption of carbon monoxide on a copper-based catalyst were
estimated by using data from in situ infrared absorption spectroscopy experiments. A direct …

Competing forces in chiral surface chemistry: enantiospecificity versus enantiomer aggregation

Y Yun, AJ Gellman - The Journal of Physical Chemistry C, 2016 - ACS Publications
The enantiospecific adsorption of enantiomer mixtures on surfaces is dictated by two
competing forces: the enantiospecificity of adsorption energetics and the propensity of …

[HTML][HTML] Chirally-modified metal surfaces: energetics of interaction with chiral molecules

P Dementyev, M Peter, S Adamovsky… - Physical Chemistry …, 2015 - pubs.rsc.org
Imparting chirality to non-chiral metal surfaces by adsorption of chiral modifiers is a highly
promising route to create effective heterogeneously catalyzed processes for the production …