Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

The interesting and diverse biological activities of nitrogen-containing compounds make the
construction of the C–N bond of great importance. Despite the tremendous advances that …

The difunctionalization of carbon–carbon double bonds, introducing two novel functional
groups onto both sides of the carbon–carbon bond in one pot, has become more and more …

Intramolecular cyclization of nitrogen-containing molecules onto pendant alkenes is an
efficient strategy for the construction of N-heterocycles, which are of paramount importance …

A method for the regiodivergent aminooxygenation of aryl olefins under electrophotocatalytic
conditions is described. The procedure employs a trisaminocyclopropenium (TAC) ion …

The Cδ− H amination of unactivated, secondary C− H bonds to form a broad range of
functionalized pyrrolidines has been developed by a triiodide (I3−)‐mediated strategy. By in …

A versatile method for the rapid synthesis of diverse enantiomerically enriched lactones has
been developed based on Cu-catalyzed enantioselective radical oxyfunctionalization of …

An efficient Mn-catalyzed aerobic oxidative hydroxyazidation of olefins for synthesis of β-
azido alcohols has been developed. The aerobic oxidative generation of azido radical …

We report a mild and efficient electrochemical protocol to access a variety of vicinally C–O
and C–N difunctionalized compounds from simple alkenes. Detailed mechanistic studies …

We disclose herein the first example of merging photoredox catalysis and copper catalysis
for radical 1, 4-carbocyanations of 1, 3-enynes. Alkyl N-hydroxyphthalimide esters are …