Photophysics of two-dimensional semiconducting organic–inorganic metal-halide perovskites

DB Straus, CR Kagan - Annual Review of Physical Chemistry, 2022 - annualreviews.org
Two-dimensional organic–inorganic hybrid perovskites (2DHPs) consist of alternating
anionic metal-halide and cationic organic layers. They have widely tunable structural and …

Uncovering the mechanisms of efficient upconversion in two-dimensional perovskites with anti-Stokes shift up to 220 meV

B Wu, A Wang, J Fu, Y Zhang, C Yang, Y Gong… - Science …, 2023 - science.org
Phonon-assisted photon upconversion holds great potential for numerous applications, eg,
optical refrigeration. However, traditional semiconductors face energy gain limitations due to …

Polarons and charge localization in metal‐halide semiconductors for photovoltaic and light‐emitting devices

LRV Buizza, LM Herz - Advanced Materials, 2021 - Wiley Online Library
Metal‐halide semiconductors have shown excellent performance in optoelectronic
applications such as solar cells, light‐emitting diodes, and detectors. In this review the role …

[HTML][HTML] Unlocking surface octahedral tilt in two-dimensional Ruddlesden-Popper perovskites

Y Shao, W Gao, H Yan, R Li, I Abdelwahab… - Nature …, 2022 - nature.com
Molecularly soft organic-inorganic hybrid perovskites are susceptible to dynamic instabilities
of the lattice called octahedral tilt, which directly impacts their carrier transport and exciton …

Brightening of dark excitons in 2D perovskites

M Dyksik, H Duim, DK Maude, M Baranowski… - Science …, 2021 - science.org
Optically inactive dark exciton states play an important role in light emission processes in
semiconductors because they provide an efficient nonradiative recombination channel …

Tuning the Excitonic Properties of the 2D (PEA)2(MA)n−1PbnI3n+1 Perovskite Family via Quantum Confinement

M Dyksik, S Wang, W Paritmongkol… - The Journal of …, 2021 - ACS Publications
In atomically thin two-dimensional (2D) crystals, the excitonic properties and band structure
scale strongly with the thickness, providing a new playground for the investigation of exciton …

Broad tunability of carrier effective masses in two-dimensional halide perovskites

M Dyksik, H Duim, X Zhu, Z Yang, M Gen… - ACS Energy …, 2020 - ACS Publications
The effective mass of charge carriers is a crucial parameter for the design of any
optoelectronic device. The estimated values of the effective mass of 2D halide perovskites …

Excitons at the phase transition of 2D hybrid perovskites

JD Ziegler, KQ Lin, B Meisinger, X Zhu… - ACS …, 2022 - ACS Publications
2D halide perovskites are among intensely studied materials platforms profiting from
solution-based growth and chemical flexibility. They feature exceptionally strong interactions …

Photophysics of two‐dimensional perovskites—learning from metal halide substitution

S Kahmann, H Duim, HH Fang, M Dyksik… - Advanced Functional …, 2021 - Wiley Online Library
Abstract 2D perovskites offers a rich playing field to explore exciton physics and they
possess a great potential for a variety of opto‐electronic applications. Whilst their …

[HTML][HTML] Manganese doping for enhanced magnetic brightening and circular polarization control of dark excitons in paramagnetic layered hybrid metal-halide …

T Neumann, S Feldmann, P Moser… - Nature …, 2021 - nature.com
Materials combining semiconductor functionalities with spin control are desired for the
advancement of quantum technologies. Here, we study the magneto-optical properties of …