This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

Difunctionalization reactions of C–C σ-bonds have the potential to streamline access to
molecules that would otherwise be difficult to prepare. However, the development of such …

Stereoselective preparation of highly substituted olefins is still a severe challenge that
requires well defined elimination precursors. Organoboron chemistry is particularly suited for …

Iterative Synthesis of Alkenes by Insertion of Lithiated Epoxides into Boronic Esters | Organic
Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters ACS …

Chain extension of boronic esters by the action of configurationally labile racemic lithium
carbenoids in the presence of scalemic bisoxazoline ligands was explored for the …

Abstract The 1, 2‐metallate rearrangement occurring with boronate complexes is a strategy
of choice for the synthesis of organoboron compounds, giving a direct access to highly …

A copper-catalyzed three-component coupling reaction of aryl iodides,
hexamethyldisilathiane and alkyl benzoates leading to alkyl aryl sulfides has been …

The synthesis of 2-sulfinyl oxetanes is described by a C–C bond-forming cyclisation
strategy. Oxetanes bearing electron-poor aryl sulfoxides are shown to be viable targets …

The first total synthesis of resveratrone and iso‐resveratrone based on an epoxide
olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated …

Thanks to the particular properties of boron, organoboron derivatives are excellent tools for
substrate-or reagent-controlled asymmetric reactions. In this chapter, we focused on the …