Possible chemical and physical scenarios towards biological homochirality
Q Sallembien, L Bouteiller, J Crassous… - Chemical Society …, 2022 - pubs.rsc.org
The single chirality of biological molecules in terrestrial biology raises more questions than
certitudes about its origin. The emergence of biological homochirality (BH) and its …
certitudes about its origin. The emergence of biological homochirality (BH) and its …
Spontaneous deracemizations
Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality
research. In the absence of any chiral inductors, an achiral substance or a racemic …
research. In the absence of any chiral inductors, an achiral substance or a racemic …
Circularly polarized light with sense and wavelengths to regulate azobenzene supramolecular chirality in optofluidic medium
Circularly polarized light (CPL) as a massless physical force causes absolute asymmetric
photosynthesis, photodestruction, and photoresolution. CPL handedness has long been …
photosynthesis, photodestruction, and photoresolution. CPL handedness has long been …
The protometabolic nature of prebiotic chemistry
N Nogal, M Sanz-Sánchez, S Vela-Gallego… - Chemical Society …, 2023 - pubs.rsc.org
The field of prebiotic chemistry has been dedicated over decades to finding abiotic routes
towards the molecular components of life. There is nowadays a handful of prebiotically …
towards the molecular components of life. There is nowadays a handful of prebiotically …
Exploring the emergence of complexity using synthetic replicators
T Kosikova, D Philp - Chemical Society Reviews, 2017 - pubs.rsc.org
A significant number of synthetic systems capable of replicating themselves or entities that
are complementary to themselves have appeared in the last 30 years. Building on an …
are complementary to themselves have appeared in the last 30 years. Building on an …
Towards homochiral supramolecular entities from achiral molecules by vortex mixing-accompanied self-assembly
Achieving homochirality is challenging both at the molecular and the supramolecular levels.
While the origin of molecular homochirality still remains mysterious, the fabrication of …
While the origin of molecular homochirality still remains mysterious, the fabrication of …
In situ mass spectrometric and kinetic investigations of Soai's asymmetric autocatalysis
O Trapp, S Lamour, F Maier, AF Siegle… - … A European Journal, 2020 - Wiley Online Library
Chemical reactions that lead to a spontaneous symmetry breaking or amplification of the
enantiomeric excess are of fundamental interest in explaining the formation of a homochiral …
enantiomeric excess are of fundamental interest in explaining the formation of a homochiral …
Spontaneous mirror symmetry breaking and origin of biological homochirality
JM Ribó, D Hochberg, J Crusats… - Journal of The …, 2017 - royalsocietypublishing.org
Recent reports on both theoretical simulations and on the physical chemistry basis of
spontaneous mirror symmetry breaking (SMSB), that is, asymmetric synthesis in the absence …
spontaneous mirror symmetry breaking (SMSB), that is, asymmetric synthesis in the absence …
Homologous and heterologous chiral supramolecular polymerization from exclusively achiral building blocks
Among the enticing issues of chiral origins are: how chirality is born from the initial achiral
units and the mechanisms for the transfer of chiral information. In this work, by combining a …
units and the mechanisms for the transfer of chiral information. In this work, by combining a …
Spontaneous mirror-symmetry breaking coupled to top-bottom chirality transfer: From porphyrin self-assembly to scalemic Diels–Alder adducts
A Arlegui, B Soler, A Galindo, O Arteaga… - Chemical …, 2019 - pubs.rsc.org
This report shows how the net supramolecular chirality that emerged by spontaneous mirror-
symmetry breaking (SMSB) at the mesoscale level can be transferred towards asymmetric …
symmetry breaking (SMSB) at the mesoscale level can be transferred towards asymmetric …