Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Metal-metal bonding interactions can engender outstanding magnetic properties in bulk
materials and molecules, and examples abound for the transition metals. Extending this …

The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

We report a monometallic dysprosium complex,[Dy (OtBu) 2 (py) 5][BPh4](5), that shows the
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …

Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …

Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states
separated by an energy barrier are among the most promising candidates for high-density …

Ever since the discovery that certain manganese clusters retain their magnetisation for
months at low temperatures, there has been intense interest in molecular nanomagnets …

Single‐molecule magnets (SMMs) are at the forefront of new technological advances in
quantum information processing and spintronics. Despite the recent impressive …