Structural flexibility in metal-organic cages

AE Martín Díaz, JEM Lewis - Frontiers in Chemistry, 2021 - frontiersin.org
Metal-organic cages (MOCs) have emerged as a diverse class of molecular hosts with
potential utility across a vast spectrum of applications. With advances in single-crystal X-ray …

A Redox‐Responsive Ferrocene‐Based Capsule Displaying Unusual Encapsulation‐Induced Charge‐Transfer Interactions

K Toyama, Y Tanaka, M Yoshizawa - Angewandte Chemie, 2023 - Wiley Online Library
A ferrocene‐based capsule is spontaneously and quantitatively formed in water by the
assembly of bent amphiphiles carrying two ferrocene units. The disassembly and assembly …

Oxidation-derived anticancer potential of sumanene–ferrocene conjugates

A Kasprzak, A Zuchowska, P Romanczuk… - Dalton …, 2024 - pubs.rsc.org
An effective synthetic protocol towards the oxidation of sumanene–ferrocene conjugates
bearing one to four ferrocene moieties has been established. The oxidation protocol was …

Ferrocene: an exotic building block for supramolecular assemblies

C Guchhait, V Suriyaa, N Sahu, SD Sarkar… - Chemical …, 2023 - pubs.rsc.org
Ferrocene (Fc), a classical organometallic complex, has found potential applications in
ligand design, catalysis, and analytical, biological, medicinal and materials chemistry. In …

Strain‐Induced Heteromorphosis Multi‐Cavity Cages: Tension‐Driven Self‐Expansion Strategy for Controllable Enhancement of Complexity in Supramolecular …

J Wang, Z Jiang, JF Yin, H Zhao, Q Dong… - Angewandte Chemie …, 2024 - Wiley Online Library
Coordinative supramolecular cages with adjustable cavities have found extensive
applications in various fields, but the cavity modification strategies for multi‐functional …

Fast, solvent-free synthesis of ferrocene-containing organic cages via dynamic covalent chemistry in the solid state

T Kunde, T Pausch, PA Guńka, M Krzyżanowski… - Chemical …, 2022 - pubs.rsc.org
A simple, solvent-free synthetic protocol towards the synthesis of organic self-assembled
macromolecules has been established. By employing mechanochemistry using glassware …

Uptake, Trapping, and Release of Organometallic Cations by Redox-Active Cationic Hosts

IF Mansoor, KG Dutton, DA Rothschild… - Journal of the …, 2021 - ACS Publications
The host–guest chemistry of metal–organic nanocages is typically driven by
thermodynamically favorable interactions with their guests such that uptake and release of …

Ferrocene-Derived Palladium (II)-Based Metallosupramolecular Structures: Synthesis, Guest Interaction, and Stimulus-Responsiveness Studies

WDJ Tremlett, T Söhnel, JD Crowley… - Inorganic …, 2023 - ACS Publications
Using ferrocene-based ligand systems, a series of heterobimetallic architectures of the
general formula [Pd m L n] x+ were designed with the aim of installing an opening and …

Self‐Assembly of a Redox Active, Metallosupramolecular [Pd3L6]6+ Complex Using a Rotationally Flexible Ferrocene Ligand

RAS Vasdev, JA Findlay, DR Turner… - Chemistry–An Asian …, 2021 - Wiley Online Library
A new ferrocene‐containing [Pd3 (L4EFc) 6] 6+(X−) 6 (C⋅ BF4 and C⋅ SbF6 where X=
BF4− or SbF6−) self‐assembled double‐walled triangle has been synthesized from the …

A Redox‐Active Phenothiazine‐based Pd2L4‐Type Coordination Cage and Its Isolable Crystalline Polyradical Cations

B Huang, M Zhou, QY Hong, MX Wu… - Angewandte …, 2024 - Wiley Online Library
Polyradical cages are of great interest because they show very fascinating physical and
chemical properties, but many challenges remain, especially for their synthesis and …