Structural flexibility in metal-organic cages
AE Martín Díaz, JEM Lewis - Frontiers in Chemistry, 2021 - frontiersin.org
Metal-organic cages (MOCs) have emerged as a diverse class of molecular hosts with
potential utility across a vast spectrum of applications. With advances in single-crystal X-ray …
potential utility across a vast spectrum of applications. With advances in single-crystal X-ray …
A Redox‐Responsive Ferrocene‐Based Capsule Displaying Unusual Encapsulation‐Induced Charge‐Transfer Interactions
K Toyama, Y Tanaka, M Yoshizawa - Angewandte Chemie, 2023 - Wiley Online Library
A ferrocene‐based capsule is spontaneously and quantitatively formed in water by the
assembly of bent amphiphiles carrying two ferrocene units. The disassembly and assembly …
assembly of bent amphiphiles carrying two ferrocene units. The disassembly and assembly …
Oxidation-derived anticancer potential of sumanene–ferrocene conjugates
A Kasprzak, A Zuchowska, P Romanczuk… - Dalton …, 2024 - pubs.rsc.org
An effective synthetic protocol towards the oxidation of sumanene–ferrocene conjugates
bearing one to four ferrocene moieties has been established. The oxidation protocol was …
bearing one to four ferrocene moieties has been established. The oxidation protocol was …
Ferrocene: an exotic building block for supramolecular assemblies
Ferrocene (Fc), a classical organometallic complex, has found potential applications in
ligand design, catalysis, and analytical, biological, medicinal and materials chemistry. In …
ligand design, catalysis, and analytical, biological, medicinal and materials chemistry. In …
Strain‐Induced Heteromorphosis Multi‐Cavity Cages: Tension‐Driven Self‐Expansion Strategy for Controllable Enhancement of Complexity in Supramolecular …
J Wang, Z Jiang, JF Yin, H Zhao, Q Dong… - Angewandte Chemie …, 2024 - Wiley Online Library
Coordinative supramolecular cages with adjustable cavities have found extensive
applications in various fields, but the cavity modification strategies for multi‐functional …
applications in various fields, but the cavity modification strategies for multi‐functional …
Fast, solvent-free synthesis of ferrocene-containing organic cages via dynamic covalent chemistry in the solid state
A simple, solvent-free synthetic protocol towards the synthesis of organic self-assembled
macromolecules has been established. By employing mechanochemistry using glassware …
macromolecules has been established. By employing mechanochemistry using glassware …
Uptake, Trapping, and Release of Organometallic Cations by Redox-Active Cationic Hosts
IF Mansoor, KG Dutton, DA Rothschild… - Journal of the …, 2021 - ACS Publications
The host–guest chemistry of metal–organic nanocages is typically driven by
thermodynamically favorable interactions with their guests such that uptake and release of …
thermodynamically favorable interactions with their guests such that uptake and release of …
Ferrocene-Derived Palladium (II)-Based Metallosupramolecular Structures: Synthesis, Guest Interaction, and Stimulus-Responsiveness Studies
WDJ Tremlett, T Söhnel, JD Crowley… - Inorganic …, 2023 - ACS Publications
Using ferrocene-based ligand systems, a series of heterobimetallic architectures of the
general formula [Pd m L n] x+ were designed with the aim of installing an opening and …
general formula [Pd m L n] x+ were designed with the aim of installing an opening and …
Self‐Assembly of a Redox Active, Metallosupramolecular [Pd3L6]6+ Complex Using a Rotationally Flexible Ferrocene Ligand
RAS Vasdev, JA Findlay, DR Turner… - Chemistry–An Asian …, 2021 - Wiley Online Library
A new ferrocene‐containing [Pd3 (L4EFc) 6] 6+(X−) 6 (C⋅ BF4 and C⋅ SbF6 where X=
BF4− or SbF6−) self‐assembled double‐walled triangle has been synthesized from the …
BF4− or SbF6−) self‐assembled double‐walled triangle has been synthesized from the …
A Redox‐Active Phenothiazine‐based Pd2L4‐Type Coordination Cage and Its Isolable Crystalline Polyradical Cations
B Huang, M Zhou, QY Hong, MX Wu… - Angewandte …, 2024 - Wiley Online Library
Polyradical cages are of great interest because they show very fascinating physical and
chemical properties, but many challenges remain, especially for their synthesis and …
chemical properties, but many challenges remain, especially for their synthesis and …