[Mn (bipyridyl)(CO) 3Br]: an abundant metal carbonyl complex as efficient electrocatalyst for CO2 reduction.

M Bourrez, F Molton, S Chardon-Noblat… - … (International ed. in …, 2011 - europepmc.org
Manganese at work: carbonyl bipyridyl complexes based on manganese, a non-noble
abundant and inexpensive metal, have been proved to be excellent molecular catalysts for …

Regulation of iron-catalyzed olefin hydroboration by ligand modifications at a remote site

KNT Tseng, JW Kampf, NK Szymczak - Acs Catalysis, 2015 - ACS Publications
An amide-derived N, N, N-Fe (II) complex catalyzes the hydroboration of alkenes at room
temperature. Alkylation of a remote site on the ligand backbone was used as a late-stage …

A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO 2 to CO

HY Kuo, TS Lee, AT Chu, SE Tignor, GD Scholes… - Dalton …, 2019 - pubs.rsc.org
Manganese (I) tricarbonyl complexes such as [Mn (bpy)(CO) 3L](L= Br, or CN) are known to
be electrocatalysts for CO2 reduction to CO. However, due to their rapid photodegradation …

Manganese-catalyzed transfer semihydrogenation of internal alkynes to E-alkenes with iPrOH as hydrogen source

A Torres-Calis, JJ García - Catalysis Science & Technology, 2022 - pubs.rsc.org
We report herein the homogeneous manganese catalyzed transfer semihydrogenation of
internal alkynes to E-alkenes using iPrOH as the hydrogen source. Manganese-based …

Hydrogenation of carboxylic esters catalyzed by manganese catalysts supported by bidentate NHC-phosphine ligands

K Azouzi, R Pointis, R Buhaibeh, PH Fernández… - Journal of …, 2024 - Elsevier
A series of bidentate manganese complexes with a general structure [(κ 2 C, PR 2 PCH 2
CH 2-NHC) Mn (CO) 3 Br](NHC= N-substituted imidazolylidene) was prepared and fully …

Reduction-induced CO dissociation by a [Mn (bpy)(CO) 4][SbF 6] complex and its relevance in electrocatalytic CO 2 reduction

HY Kuo, SE Tignor, TS Lee, D Ni, JE Park… - Dalton …, 2020 - pubs.rsc.org
[Mn (bpy)(CO) 3Br] is recognized as a benchmark electrocatalyst for CO2 reduction to CO,
with the doubly reduced [Mn (bpy)(CO) 3]− proposed to be the active species in the catalytic …

Mono-and bimetallic manganese–carbonyl complexes and clusters bearing imidazol (in) ium-2-dithiocarboxylate ligands

TF Beltrán, G Zaragoza, L Delaude - Dalton Transactions, 2017 - pubs.rsc.org
Five complexes with the generic formula fac-[MnBr (CO) 3 (S2C· NHC)] were obtained by
reacting [MnBr (CO) 5] with a set of representative imidazol (in) ium-2-dithiocarboxylate …

Correlations between photophysical and electrochemical properties for a series of new Mn carbonyl complexes containing substituted phenanthroline ligands

DA Kurtz, B Dhakal, RJ Hulme, GS Nichol… - Inorganica Chimica …, 2015 - Elsevier
Three new complexes of the type Mn (NN)(CO) 3 Br have been synthesized, where NN= 5-
substituted-1, 10-phenanthroline. The novel compounds have been characterized by 1 H …

Extending the π‐System in MnI Diimine Tricarbonyl Complexes: Impacts on Photochemistry, Electrochemistry, and CO2 Catalytic Reduction Activity

KY Cohen, R Evans, AB Bocarsly - European Journal of …, 2023 - Wiley Online Library
Abstract The complex [Mn (bpy)(CO) 3Br], has been previously studied as both an
electrocatalyst and a photocatalyst, in conjugation with a photosensitizer, for CO2 reduction …

Synthesis and characterization of Mn (I) complexes and their larvicidal activity against Aedes aegypti, vector of dengue fever

I de Aguiar, ER dos Santos, AC Mafud, V Annies… - Inorganic chemistry …, 2017 - Elsevier
This article describes the structure (X-ray), spectroscopic properties (FTIR, UV–vis, 1 H
NMR) and larvicidal activity of Mn (I) complexes, fac-[Mn (CO) 3 (phen)(L)]+, where phen= 1 …