Silica-supported metal complex catalysts have been developed and used for organic
transformations. The surface environment around the supported metal complex enhances …

Process intensification is a cornerstone to achieve a significant reduction in energy
consumption and CO2 emissions in the chemical industry. In this context, a monolithic …

This highlight article focuses on the rapidly emerging area of electrocatalytic metal–organic
frameworks (MOFs) with a particular emphasis on those systems displaying intrinsic activity …

Solution-phase catalysis using molecular transition metal complexes is an extremely
powerful tool for chemical synthesis and a key technology for sustainable manufacturing …

The supported ionic liquid phase (SILP) concept, which included thin films of ionic liquid
dispersed onto porous support surfaces, was applied for the gas‐phase hydroformylation of …

For the industrially relevant hydroformylation of but‑1-ene the concept of supported ionic
liquid phase (SILP) has been applied previously. In this work, we have studied the influence …

We report the application of nitrogen doped carbon (NDC) materials as supports for the SILP
catalyzed gas-phase hydroformylation of ethylene. The Rh–xantphos complex, dissolved in …

Several supported liquid-phase (SLP) catalysts with immobilized Rh-biphephos complexes
on monolithic supports were prepared and applied for continuous gas-phase …

A novel gas‐phase process has been developed that allows direct two‐step conversion of
butane into pentanals with high activity and selectivity. The process consists of alkane …

This review focuses on the development of continuous rhodium-catalyzed hydroformylations
in the past 15 years. Recent progresses are discussed and compared in detail, based on …