Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …

For a long time, Zintl ions of Group 14 and 15 elements were considered to be remarkable
species domiciled in solid‐state chemistry that have unexpected stoichiometries and …

The generation and handling of the light-sensitive and metastable yellow arsenic (As4) is
extremely challenging. In view of recent breakthroughs in synthesizing As4 storage …

Inorganic metallocene derivatives containing only cyclo-P n ligands have been targeted for
more than 20 years, but their syntheses have never been achieved by pursuing the …

Lange Zeit betrachtete man die Zintl‐Ionen der Elemente der 14. und 15. Gruppe für
bemerkenswerte, in der Festkörperchemie angesiedelte Spezies, die einerseits durch ihre …

The controlled chemical activation of white phosphorus (P4) is a versatile, albeit often
unpredictable, route to phosphoruscontaining species of varied nuclearities. This area of …

The solution chemistry of Group 14 Zintl-type clusters is of growing interest as a result of
their potential to be used as molecular building blocks for the construction of nanoscale …

Originally, the concepts of aromaticity and antiaromaticity were introduced to explain the
stability and reactivity of unsaturated organic compounds. Since then, they have been …

The synthesis and isolation of the 2‐arsaethynolate anion, AsCO−, and its subsequent
reactivity towards heteroallenes is reported. Reactions with ketenes and carbodiimides …

Bimetallic species with formal bond orders higher than four have been known as chemical
curiosities for decades.[1] Molecules like Cr2 had been stabilized in inert matrices at low …