C–H activation

T Rogge, N Kaplaneris, N Chatani, J Kim… - Nature Reviews …, 2021 - nature.com
Transition metal-catalysed C–H activation has emerged as an increasingly powerful platform
for molecular syntheses, enabling applications to natural product syntheses, late-stage …

First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Photoinduced borylation for the synthesis of organoboron compounds: focus review

YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Recent developments in organoboron chemistry: old dogs, new tricks

JWB Fyfe, AJB Watson - Chem, 2017 - cell.com
Organoboron reagents are one of the most widely studied and applied classes of reagent
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …

Selection of boron reagents for Suzuki–Miyaura coupling

AJJ Lennox, GC Lloyd-Jones - Chemical Society Reviews, 2014 - pubs.rsc.org
Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

Borylation and silylation of C–H bonds: a platform for diverse C–H bond functionalizations

JF Hartwig - Accounts of chemical research, 2012 - ACS Publications
Methods that functionalize C–H bonds can lead to new approaches for the synthesis of
organic molecules, but to achieve this goal, researchers must develop site-selective …

C− H activation for the construction of C− B bonds

IAI Mkhalid, JH Barnard, TB Marder, JM Murphy… - Chemical …, 2010 - ACS Publications
A long-standing challenge in synthetic chemistry is the direct, selective functionalization of
alkyl, alkenyl, and aryl CH bonds. Much research has been devoted to the selective …

Nickel-catalyzed cross-couplings involving carbon− oxygen bonds

BM Rosen, KW Quasdorf, DA Wilson, N Zhang… - Chemical …, 2011 - ACS Publications
REVIEW intricate molecular topologies and architectures. To turn the molecular dreams into
a reality, synthetic chemists must ultimately roll up their sleeves and become molecular …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …