Donor/donor carbenes are relatively new in the field of carbene chemistry; although
applications in C− H and X− H insertion reactions are few in number, they demonstrate …

Transition‐metal‐catalyzed reactions of N‐tosylhydrazones provide a convenient access to
various molecules by novel carbon‐carbon or carbon‐heteroatom bond formations via …

A Pd-catalyzed enantioselective three-component reaction of N-sulfonylhydrazones, aryl
bromides, and silylboronic esters is developed, enabling the synthesis of chiral gem …

We report the first example of enantioselective, intermolecular diarylcarbene insertion into Si–
H bonds for the synthesis of silicon-stereogenic silanes. Dirhodium (II) carboxylates catalyze …

The palladium-catalyzed oxidative borylation reaction of N-tosylhydrazones has been
developed. The reaction features mild conditions, broad substrate scope, and good …

A novel photocatalytic method for the preparation of diarylmethyl silanes was reported
through silyl radicals addition strategy to p-QMs (p-quinone methides). This protocol could …

The development of novel strategies for the efficient incorporation of germanium into
widespread molecular structures, especially for the synthesis of potentially bioactive …

Transition metal-catalyzed enantioselective transfer reactions of carbenes constitute an
important tool for constructing various chemical bonds. In past decades, enantioselective …

Under metal-and ligand-free conditions, the economical and accessible CF3SO3H
successfully catalyzed homogeneous O–H bond insertion reactions between hydroxyl …

While metal carbene-mediated Si–H insertion reactions have become a powerful strategy to
build new C–Si bonds, the utilization of α-aminocarbene intermediates generated from …