The fluoride-assisted ethynylation of ketones and aldehydes is described using
commercially available calcium carbide with typically 5 mol% of TBAF· 3H2O as the catalyst …

The mechanisms of fundamental base‐promoted acetylene reactions, namely, nucleophilic
addition to the triple C≡ C bond (vinylation) and nucleophilic addition of acetylenic …

The unique reactivity of the acetylenic unit in DMSO gives rise to ubiquitous synthetic
methods. We theoretically consider CaC2 solubility and protolysis in DMSO and formulate a …

A rapidly developing approach adding new dimensions to acetylene chemistry relying on
employment of high basicity media such as alkali metal hydroxide suspensions in dimethyl …

The mechanism of aldol condensation of ketones in KOH/DMSO superbasic media has
been investigated using the B2PLYP (D2)/6-311+ G**//B3LYP/6-31+ G* quantum-chemical …

Carbohydrate‐based benzylidene acetals undergo reductive ring opening. 1‐β‐O‐Acyl
glucoside conjugates of phenylacetic acids have been synthesized, and their acyl migration …

The mechanism of one-pot assembly of tetracyclic derivatives of frontalin from cycloaliphatic
ketones and acetylene, in superbasic KOH/DMSO medium has been investigated using the …

The aim of the research work is the development of synthesis methods of aromatic acetylene
alcohols and their various derivatives using different catalytic systems and also, determining …

В обзоре рассмотрены динамика развития и синтетическое применение в
органическом синтезе недавно открытой реакции ацетиленовых карбанионов …

The mechanism of formation of 1, 5-diketone, a key intermediate in the stereoselective
assembly of 2, 3, 4-trimethyl-7-methylidene-1, 5-di (thiophen-2-yl)-6, 8-dioxabicyclo [3.2. 1] …