Applications of the method of continuous variations (MCV or the Method of Job) to problems
of interest to organometallic chemists are described. MCV provides qualitative and …

Copper complexes are highly versatile species that find promising uses in broad fields such
as catalysis, drug design, and bioinorganic applications. However, copper complexes …

Transition metal complexes that incorporate crown ethers into the supporting ligands have
emerged as a powerful class of catalysts capable of cation-tunable reactivity. Cations held in …

The thermochemistry of cation–macrocycle interactions in nickel pincer complexes bearing a
hemilabile aza-15-crown-5 or aza-18-crown-6 macrocycle is investigated and applied to …

Several new iridium (I) and iridium (III) carbonyl complexes supported by aminophosphinite
pincer ligands have been prepared and characterized. A surprising diversity of reaction …

Abstract Chalcogenolato-bridged Re (I)-based dinuclear metallacrown ethers [{(CO) 3 Re (µ-
ER) 2 Re (CO) 3}(µ-L)](E= S, Se; R= tolyl, benzyl)(1–4) were accomplished in a single-step …

Abstract Dieser Aufsatz beschreibt Anwendungen der Methode der kontinuierlichen
Variation (MCV oder Job‐Plots) auf Fragen der metallorganischen Chemie. Die MCV bietet …

Chemical solution-phase equilibria such as acid/base reactions and complex formation are
typically investigated by titration studies that either use in situ analysis of a continuously …

Herein is reported the effect of different polyether binders (alkali metal, alkaline earth metal,
and lanthanide salts) as regulation agents to enhance the catalytic properties of palladium …

Ligand binding by macromolecules represents a core event of broad relevance to a range of
systems, including catalytic systems alongside noncatalytic systems such as nucleic acid …