Desulfonylation via radical process: recent developments in organic synthesis

XQ Chu, D Ge, YY Cui, ZL Shen, CJ Li - Chemical reviews, 2021 - ACS Publications
As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Metal-involving synthesis and reactions of oximes

DS Bolotin, NA Bokach, MY Demakova… - Chemical …, 2017 - ACS Publications
This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …

Uses of K2S2O8 in Metal-Catalyzed and Metal-Free Oxidative Transformations

S Mandal, T Bera, G Dubey, J Saha, JK Laha - ACS Catalysis, 2018 - ACS Publications
Carbon–carbon/carbon–heteroatom bond formation via oxidative transformations is a
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …

Silver-catalyzed decarboxylative trifluoromethylation of aliphatic carboxylic acids

X Tan, Z Liu, H Shen, P Zhang… - Journal of the American …, 2017 - ACS Publications
The silver-catalyzed decarboxylative trifluoromethylation of aliphatic carboxylic acids is
described. With AgNO3 as the catalyst and K2S2O8 as the oxidant, the reactions of aliphatic …

Wonderful fusion of organofluorine chemistry and decarboxylation strategy

P Xiao, X Pannecoucke, JP Bouillon… - Chemical Society …, 2021 - pubs.rsc.org
Decarboxylation strategy has been emerging as a powerful tool for the synthesis of fluorine-
containing organic compounds that play important roles in various fields such as …

Radical acylation: concepts, synthetic applications and directions

Y Zhang, Y Zhang, J Lin, Z Li, H Huang - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Ketones can serve as prevalent structural cores in natural products, pharmaceuticals, and
materials science. The synthesis of ketones is one of the most commonly addressed …

Silver‐Based Radical Reactions: Development and Insights

G Fang, X Cong, G Zanoni, Q Liu… - Advanced Synthesis & …, 2017 - Wiley Online Library
Silver‐mediated reactions have recently emerged as a frontier area in organic chemistry.
Indeed, the remarkable property of silver as a single‐electron oxidant has led to its …

Deacylation-aided C–H alkylative annulation through C–C cleavage of unstrained ketones

X Zhou, Y Xu, G Dong - Nature catalysis, 2021 - nature.com
Arene-and heteroarene-fused rings are pervasive in biologically active molecules. Direct
annulation between a C–H bond on the aromatic core and a tethered alkyl moiety provides a …

Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols

Y Zhu, K Huang, J Pan, X Qiu, X Luo, Q Qin… - Nature …, 2018 - nature.com
Aliphatic alcohols are common and bulk chemicals in organic synthesis. The site-selective
functionalization of non-activated aliphatic alcohols is attractive but challenging. Herein, we …

Copper‐Mediated Decarboxylative Coupling of Benzamides with ortho‐Nitrobenzoic Acids by Directed C−H Cleavage

K Takamatsu, K Hirano, M Miura - Angewandte Chemie, 2017 - Wiley Online Library
A copper‐mediated decarboxylative coupling of benzamides with ortho‐nitrobenzoic acids
by 8‐aminoquinoline‐directed C− H cleavage has been developed. This reaction proceeds …