Desulfonylation via radical process: recent developments in organic synthesis
XQ Chu, D Ge, YY Cui, ZL Shen, CJ Li - Chemical reviews, 2021 - ACS Publications
As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …
merged with various types of reactions for the efficient construction of diverse molecular …
Metal-involving synthesis and reactions of oximes
DS Bolotin, NA Bokach, MY Demakova… - Chemical …, 2017 - ACS Publications
This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …
Uses of K2S2O8 in Metal-Catalyzed and Metal-Free Oxidative Transformations
Carbon–carbon/carbon–heteroatom bond formation via oxidative transformations is a
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …
Silver-catalyzed decarboxylative trifluoromethylation of aliphatic carboxylic acids
The silver-catalyzed decarboxylative trifluoromethylation of aliphatic carboxylic acids is
described. With AgNO3 as the catalyst and K2S2O8 as the oxidant, the reactions of aliphatic …
described. With AgNO3 as the catalyst and K2S2O8 as the oxidant, the reactions of aliphatic …
Wonderful fusion of organofluorine chemistry and decarboxylation strategy
P Xiao, X Pannecoucke, JP Bouillon… - Chemical Society …, 2021 - pubs.rsc.org
Decarboxylation strategy has been emerging as a powerful tool for the synthesis of fluorine-
containing organic compounds that play important roles in various fields such as …
containing organic compounds that play important roles in various fields such as …
Radical acylation: concepts, synthetic applications and directions
Y Zhang, Y Zhang, J Lin, Z Li, H Huang - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Ketones can serve as prevalent structural cores in natural products, pharmaceuticals, and
materials science. The synthesis of ketones is one of the most commonly addressed …
materials science. The synthesis of ketones is one of the most commonly addressed …
Silver‐Based Radical Reactions: Development and Insights
G Fang, X Cong, G Zanoni, Q Liu… - Advanced Synthesis & …, 2017 - Wiley Online Library
Silver‐mediated reactions have recently emerged as a frontier area in organic chemistry.
Indeed, the remarkable property of silver as a single‐electron oxidant has led to its …
Indeed, the remarkable property of silver as a single‐electron oxidant has led to its …
Deacylation-aided C–H alkylative annulation through C–C cleavage of unstrained ketones
Arene-and heteroarene-fused rings are pervasive in biologically active molecules. Direct
annulation between a C–H bond on the aromatic core and a tethered alkyl moiety provides a …
annulation between a C–H bond on the aromatic core and a tethered alkyl moiety provides a …
Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols
Aliphatic alcohols are common and bulk chemicals in organic synthesis. The site-selective
functionalization of non-activated aliphatic alcohols is attractive but challenging. Herein, we …
functionalization of non-activated aliphatic alcohols is attractive but challenging. Herein, we …
Copper‐Mediated Decarboxylative Coupling of Benzamides with ortho‐Nitrobenzoic Acids by Directed C−H Cleavage
K Takamatsu, K Hirano, M Miura - Angewandte Chemie, 2017 - Wiley Online Library
A copper‐mediated decarboxylative coupling of benzamides with ortho‐nitrobenzoic acids
by 8‐aminoquinoline‐directed C− H cleavage has been developed. This reaction proceeds …
by 8‐aminoquinoline‐directed C− H cleavage has been developed. This reaction proceeds …