[HTML][HTML] Transition metal-catalyzed branch-selective hydroformylation of olefins in organic synthesis

Y Ning, T Ohwada, FE Chen - Green Synthesis and Catalysis, 2021 - Elsevier
Hydroformylation of olefins can generate linear and branched aldehydes, and the branched
aldehydes are attractive precursors for the synthesis of fine chemicals and pharmaceuticals …

Polyene natural products

C Thirsk, A Whiting - Journal of the Chemical Society, Perkin …, 2002 - pubs.rsc.org
Polyene natural products - Journal of the Chemical Society, Perkin Transactions 1 (RSC
Publishing) DOI:10.1039/B109741P Royal Society of Chemistry View PDF VersionPrevious …

Photoredox‐catalyzed reductive coupling of aldehydes, ketones, and imines with visible light

M Nakajima, E Fava, S Loescher… - Angewandte Chemie …, 2015 - Wiley Online Library
Ketyl radical and amino radical anions, valuable reactive intermediates for C C bond‐
forming reactions, are accessible through a C O/C NR umpolung. However, their …

Construction of CC bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300 (Cr)

T Luo, L Li, Y Chen, J An, C Liu, Z Yan… - Nature …, 2021 - nature.com
Construction of CC bonds via reductive coupling of aldehydes and ketones is hindered by
the highly negative reduction potential of these carbonyl substrates, particularly ketones …

Advances in solution-and solid-phase synthesis toward the generation of natural product-like libraries

JP Nandy, M Prakesch, S Khadem, PT Reddy… - Chemical …, 2009 - ACS Publications
There is a growing interest in the use of small molecules as chemical probes in parallel to
classical genomic tools (gene expression, gene profiling, gene knockouts, and siRNA-based …

Unconventional macrocyclizations in natural product synthesis

I Saridakis, D Kaiser, N Maulide - ACS Central Science, 2020 - ACS Publications
Over the past several decades, macrocyclic compounds have emerged as increasingly
significant therapeutic candidates in drug discovery. Their pharmacological activity hinges …

Heronamides A–C, new polyketide macrolactams from an Australian marine-derived Streptomyces sp. A biosynthetic case for synchronized tandem electrocyclization

R Raju, AM Piggott, MM Conte… - Organic & Biomolecular …, 2010 - pubs.rsc.org
A Streptomyces sp. isolated from a shallow water sediment sample collected off Heron
Island, Australia, afforded three new polyketide macrolactams, heronamides A–C (1–3) …

Visible Light Induced Reduction and Pinacol Coupling of Aldehydes and Ketones Catalyzed by Core/Shell Quantum Dots

ZW Xi, L Yang, DY Wang, CW Feng, Y Qin… - The Journal of …, 2021 - ACS Publications
We present an efficient and versatile visible light-driven methodology to transform aryl
aldehydes and ketones chemoselectively either to alcohols or to pinacol products with …

Photo-catalyst-free photomediated pinacol coupling of ketones/aldehydes by formate at room temperature

Q Shen, K Cao, X Chen, X Li, N Zhang, YB Miao… - Green Chemistry, 2023 - pubs.rsc.org
In this work, a highly effective metal-free and photo-catalyst-free method for the reductive
coupling of carbonyl compounds to produce pinacols using formate under photoirradiation …

Structure and Biological Activity of 8-Deoxyheronamide C from a Marine-Derived Streptomyces sp.: Heronamides Target Saturated Hydrocarbon Chains in Lipid …

R Sugiyama, S Nishimura, N Matsumori… - Journal of the …, 2014 - ACS Publications
Polyene macrolactams are a class of microbial metabolites, many of which show potent
biological activities with unidentified modes of action. Here we report that 8 …