Stereochemical modulation of ketyl radical cyclization enabled by pyridine-boryl radicals: catalytic diastereoselective synthesis of trans-2-alkyl-1-indanols

S Kim, J Jo, S Lee, W Chung - Chemical Communications, 2023 - pubs.rsc.org
Previously available ketyl radical cyclization conditions suffer from low and uncontrollable
diastereoselectivity because of the absence of reagent–substrate interactions. In this report …

Study on Pyridine-Boryl Radical-Promoted, Ketyl Radical-Mediated Carbon–Carbon Bond-Forming Reactions

J Jo, S Kim, S Park, S Kim, S Lee… - The Journal of …, 2024 - ACS Publications
Ketyl radicals are synthetically versatile reactive species, but their applications have been
hampered by harsh generation conditions employing highly reducing metals. Recently, the …

One‐Pot Access to Sulfonyl 2,3‐Diarylnaphthalenes via tBuOK‐Mediated Benzannulation of o‐Bis‐sulfonylmethyl Arenes with Diarylacetylenes

MY Chang, NC Hsueh - Advanced Synthesis & Catalysis, 2024 - Wiley Online Library
One‐pot access to sulfonyl 2, 3‐diarylnaphthalenes was developed via tBuOK‐mediated (4+
2) benzannulation of o‐bis‐sulfonylmethyl arenes, employing diverse diarylacetylenes. A …

One‐Pot Access to Sulfonyl 2‐Arylnaphthalenes via Wacker Oxidation of Sulfonyl o‐Allylchalcones

NC Hsueh, MC Tsai, MY Chang - Advanced Synthesis & …, 2020 - Wiley Online Library
Under the oxygen atmosphere conditions, PdCl2/CuCl2‐mediated one‐pot Wacker‐type
decarboxylative benzannulation of sulfonyl o‐allylchalcones provides sulfonyl naphthalenes …