A comprehensive review on lignin pyrolysis: Mechanism, modeling and the effects of inherent metals in biomass
This work comprehensively reviews the pyrolysis of lignin from the aspects of mechanism,
modeling, and effects of inorganic species. Initially, the lignin general pyrolysis …
modeling, and effects of inorganic species. Initially, the lignin general pyrolysis …
[HTML][HTML] Occurrence, formation, environmental fate and risks of environmentally persistent free radicals in biochars
Biochars are used globally in agricultural crop production and environmental remediation.
However, environmentally persistent free radicals (EPFRs), which are stable emerging …
However, environmentally persistent free radicals (EPFRs), which are stable emerging …
Hydrothermal and pyrolytic conversion of biomasses into catalysts for advanced oxidation treatments
X He, N Zheng, R Hu, Z Hu… - Advanced Functional …, 2021 - Wiley Online Library
Biomasses are very important natural products. Transferring biomass into catalysts for the
advanced oxidation process (AOP) via heat treatment has attracted extensive attention. This …
advanced oxidation process (AOP) via heat treatment has attracted extensive attention. This …
Bio-based platform chemicals synthesized from lignin biorefinery
R Hu, J Zhan, Y Zhao, X Xu, G Luo, J Fan, JH Clark… - Green …, 2023 - pubs.rsc.org
Bio-based chemicals synthesized by lignin offer a promising pathway of bioenergy utilization
to achieve the target of the Paris Agreement with< 2° C of climate warming temperature …
to achieve the target of the Paris Agreement with< 2° C of climate warming temperature …
Applications, impacts, and management of biochar persistent free radicals: A review
R Zhang, R Zhang, AR Zimmerman, H Wang… - Environmental Pollution, 2023 - Elsevier
Biochar is a promising environmental contaminant remediation agent because of its
adsorptive and catalytic properties. However, the environmental effects of persistent free …
adsorptive and catalytic properties. However, the environmental effects of persistent free …
Measuring biomass fast pyrolysis kinetics: State of the art
G SriBala, HH Carstensen… - Wiley …, 2019 - Wiley Online Library
Fast pyrolysis of lignocellulosic biomass is considered to be a promising thermochemical
route for the production of drop‐in fuels and valuable chemicals. During the past decades, a …
route for the production of drop‐in fuels and valuable chemicals. During the past decades, a …
EPR detection of key radicals during coking process of lignin monomer pyrolysis
Q Zhou, Z Luo, G Li, S Li - Journal of Analytical and Applied Pyrolysis, 2020 - Elsevier
Lignin pyrolysis is a promising method for the sustainable production of phenolic
compounds from biomass. However, detailed knowledge about the radicals involved in this …
compounds from biomass. However, detailed knowledge about the radicals involved in this …
Non-catalytic oxidative depolymerization of lignin in perfluorodecalin to produce phenolic monomers
We demonstrate for the first time non-catalytic, oxidative cracking with molecular oxygen
(O2) to depolymerize native lignin into oxygenated phenolic monomers. Maximum monomer …
(O2) to depolymerize native lignin into oxygenated phenolic monomers. Maximum monomer …
Metal-free biomass-derived environmentally persistent free radicals (Bio-EPFRs) from lignin pyrolysis
To assess contribution of the radicals formed from biomass burning, our recent findings
toward the formation of resonantly stabilized persistent radicals from hydrolytic lignin …
toward the formation of resonantly stabilized persistent radicals from hydrolytic lignin …
Molecular Products and Fundamentally Based Reaction Pathways in the Gas-Phase Pyrolysis of the Lignin Model Compound p-Coumaryl Alcohol
The fractional pyrolysis of lignin model compound para-coumaryl alcohol (p-CMA)
containing a propanoid side chain and a phenolic OH group was studied using the System …
containing a propanoid side chain and a phenolic OH group was studied using the System …