Heterogenised Molecular Catalysts for Sustainable Electrochemical CO2 Reduction
D Grammatico, AJ Bagnall, L Riccardi… - Angewandte …, 2022 - Wiley Online Library
There has been a rapid rise in interest regarding the advantages of support materials to
protect and immobilise molecular catalysts for the carbon dioxide reduction reaction …
protect and immobilise molecular catalysts for the carbon dioxide reduction reaction …
Molecular engineering of metal complexes for electrocatalytic carbon dioxide reduction: From adjustment of intrinsic activity to molecular immobilization
ZW Yang, JM Chen, LQ Qiu, WJ Xie… - Angewandte Chemie …, 2022 - Wiley Online Library
The electrocatalytic CO2 reduction reaction (ECO2RR) is one promising method for storing
intermittent clean energy in chemical bonds and producing fuels. Among various kinds of …
intermittent clean energy in chemical bonds and producing fuels. Among various kinds of …
Carbon‐Supported Single Metal Site Catalysts for Electrochemical CO2 Reduction to CO and Beyond
The electrochemical CO2 reduction reaction (CO2RR) is a promising strategy to achieve
electrical‐to‐chemical energy storage while closing the global carbon cycle. The carbon …
electrical‐to‐chemical energy storage while closing the global carbon cycle. The carbon …
Adsorbed cobalt porphyrins act like metal surfaces in electrocatalysis
Electrodes chemically modified with molecular active sites are potent catalysts for energy
conversion reactions. Such electrodes are typically presumed to operate by the same redox …
conversion reactions. Such electrodes are typically presumed to operate by the same redox …
Hybridization of Molecular and Graphene Materials for CO2 Photocatalytic Reduction with Selectivity Control
In the quest for designing efficient and stable photocatalytic materials for CO2 reduction,
hybridizing a selective noble-metal-free molecular catalyst and carbon-based light …
hybridizing a selective noble-metal-free molecular catalyst and carbon-based light …
Supramolecular tuning enables selective oxygen reduction catalyzed by cobalt porphyrins for direct electrosynthesis of hydrogen peroxide
We report a supramolecular strategy for promoting the selective reduction of O2 for direct
electrosynthesis of H2O2. We utilized cobalt tetraphenylporphyrin (Co‐TPP), an oxygen …
electrosynthesis of H2O2. We utilized cobalt tetraphenylporphyrin (Co‐TPP), an oxygen …
Organic–Inorganic Hybrid Nanomaterials for Electrocatalytic CO2 Reduction
Electrochemical CO2 reduction (ECR) to value‐added chemicals and fuels is regarded as
an effective strategy to mitigate climate change caused by CO2 from excess consumption of …
an effective strategy to mitigate climate change caused by CO2 from excess consumption of …
Electrosynthesis of syngas via the co-reduction of CO2 and H2O
The traditional synthesis of syngas, a mixture of CO and H 2, relies on the reverse water gas
shift reaction at high temperature and thus consumes considerable energy and resources. In …
shift reaction at high temperature and thus consumes considerable energy and resources. In …
Electrocatalytic CO2 Reduction: from Discrete Molecular Catalysts to Their Integrated Catalytic Materials
K Lei, B Yu Xia - Chemistry–A European Journal, 2022 - Wiley Online Library
Molecular catalysts (metal complexes), with molecularly defined uniform active sites and
atomically precise structural tailorability allowing for regulating catalytic performance …
atomically precise structural tailorability allowing for regulating catalytic performance …
Mechanistic Insights into Co and Fe Quaterpyridine-Based CO2 Reduction Catalysts: Metal–Ligand Orbital Interaction as the Key Driving Force for Distinct Pathways
M Loipersberger, DGA Cabral, DBK Chu… - Journal of the …, 2021 - ACS Publications
Both [CoII (qpy)(H2O) 2] 2+ and [FeII (qpy)(H2O) 2] 2+(with qpy= 2, 2′: 6′, 2 ″: 6′′, 2‴-
quaterpyridine) are efficient homogeneous electrocatalysts and photoelectrocatalysts for the …
quaterpyridine) are efficient homogeneous electrocatalysts and photoelectrocatalysts for the …