3 Advances in the coordination chemistry of amidinate and guanidinate ligands

FT Edelmann - Advances in organometallic chemistry, 2008 - books.google.com
The quest for alternatives to cyclopentadienyl-based ligands has led to a recent renaissance
of N-centered donor ligands in various fields of organometallic and coordination chemistry …

Metal complexes of chelating diarylamido phosphine ligands

LC Liang - Coordination chemistry reviews, 2006 - Elsevier
This review summarizes the recent progress in coordination and organometallic chemistry
involving metal complexes of chelating diarylamido phosphine ligands, including bidentate …

Structure and Reactivity of Late Transition Metal η3‐Benzyl Complexes

BM Trost, LC Czabaniuk - Angewandte Chemie International …, 2014 - Wiley Online Library
The coordination of transition metals to organic fragments can yield complexes with
fascinating and unexpected binding patterns. The study of metal‐benzyl complexes has …

Guanidinates as Alternative Ligands for Organometallic Complexes

F Carrillo-Hermosilla, R Fernández-Galán, A Ramos… - Molecules, 2022 - mdpi.com
For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have
dominated Coordination and Organometallic Chemistry. At the same time, alternative …

Evaluating f‐element bonding from structure and thermodynamics

SG Minasian, JL Krinsky… - Chemistry–A European …, 2011 - Wiley Online Library
The practical goal to measure and understand the thermodynamic properties of molecules
and materials containing f‐elements is often achieved through indirect methods. Of the …

Synthesis, structural investigation, and reactivity of neutral and cationic bis (guanidinato) zirconium (IV) complexes

AP Duncan, SM Mullins, J Arnold, RG Bergman - Organometallics, 2001 - ACS Publications
The mono (guanidinato) complex Cp (guan) ZrCl2 (1; guan= η2-(iPrN) 2C (NMe2)) was
prepared by treatment of CpZrCl3 (Cp= η5-C5H5) with the in situ generated lithium …

Crystal Environments Probed by EPR Spectroscopy. Variations in the EPR Spectra of CoII(octaethylporphyrin) Doped in Crystalline Diamagnetic Hosts and a …

A Ozarowski, HM Lee, AL Balch - Journal of the American …, 2003 - ACS Publications
The powder and single-crystal EPR spectra of CoII (OEP)(OEP is the dianion of
octaethylporphyrin) doped into a range of diamagnetic crystals including simple four …

Neutral and cationic N-heterocyclic carbene zirconium and hafnium benzyl complexes: Highly regioselective oligomerization of 1-hexene with a preference for trimer …

S Dagorne, S Bellemin-Laponnaz, C Romain - Organometallics, 2013 - ACS Publications
Various zirconium and hafnium amido, chloro, and benzyl complexes supported by a
tridentate N-heterocyclic carbene bis-phenolate dianionic ligand ((OCO) 2–) have been …

Trisguanidinate lanthanide complexes: syntheses, structures, and catalytic activity for mild amidation of aldehydes with amines

C Qian, X Zhang, J Li, F Xu, Y Zhang, Q Shen - Organometallics, 2009 - ACS Publications
A series of new trisguanidinate lanthanide complexes including the first THF-solvated
trisguanidinate lanthanum complexes were synthesized and fully characterized. The …

A thorium chalcogenolate series generated by atom insertion into thorium–carbon bonds

NS Settineri, ME Garner, J Arnold - Journal of the American …, 2017 - ACS Publications
A new thorium monoalkyl complex, Th (CH2SiMe3)(L3)(L= MeC (N i Pr) 2)(2), undergoes
insertion of chalcogen atoms resulting in a series of thorium chalcogenolate complexes, Th …