Upcycling aromatic polymers through C–H fluoroalkylation

SE Lewis, BE Wilhelmy, FA Leibfarth - Chemical science, 2019 - pubs.rsc.org
The unique properties imparted by planar, rigid aromatic rings in synthetic polymers make
these macromolecules useful in a range of applications, including disposable packaging …

A novel strategy for accelerating degradation of proton exchange membranes in fuel cell

W Yang, H Guo, F Niu, B Wang, B Huang, S Niu, J Liu… - Renewable Energy, 2023 - Elsevier
Conventional proton exchange membrane (PEM) durability testing takes thousands of
hours, which is consuming and costly. The development of a suitable accelerated aging …

Elucidations of Structure and Molecular Dynamics of Complex Polymers by State-of-the-Art Solid-State NMR Spectroscopy

R Zhang, W Chen, T Miyoshi - Macromolecules, 2024 - ACS Publications
Solid-state nuclear magnetic resonance (ssNMR) has been playing an indispensable role in
revealing the interplay of structure and molecular dynamics in polymers at different states. In …

High-resolution Overhauser dynamic nuclear polarization enhanced proton NMR spectroscopy at low magnetic fields

TJ Keller, AJ Laut, J Sirigiri, T Maly - Journal of Magnetic Resonance, 2020 - Elsevier
Dynamic nuclear polarization (DNP) has gained large interest due to its ability to increase
signal intensities in nuclear magnetic resonance (NMR) experiments by several orders of …

Changes of coordination modes of Cu-based coordination complexes as tuneable proton-conducting solid electrolytes

MJ Wei, JQ Fu, YD Wang, JY Gu, BL Liu… - Journal of Materials …, 2017 - pubs.rsc.org
It is essential and vital to develop high-performance proton-conducting solid electrolyte
materials for proton exchange membrane fuel cells (PEMFCs), but it remains challenging to …

[HTML][HTML] Measuring the water content of polymer electrolyte membranes using double points of proton magic angle spinning nuclear magnetic resonance data

RY Hwang, Y Moon, HM Kim, E Kim, S Park, OH Han - Polymer, 2024 - Elsevier
Although the water content in polymer electrolyte membranes (PEMs) is a very important
parameter for controlling their performance, measuring it is difficult because strong acidic …

Overhauser dynamic nuclear polarization (ODNP)-enhanced two-dimensional proton NMR spectroscopy at low magnetic fields

TJ Keller, T Maly - Magnetic Resonance, 2021 - mr.copernicus.org
The majority of low-field Overhauser dynamic nuclear polarization (ODNP) experiments
reported so far have been 1D NMR experiments to study molecular dynamics and in …

[HTML][HTML] Flow NMR system development for real-time in situ multiple detection of direct methanol fuel cell exhausts

RY Hwang, OH Han - Electrochemistry Communications, 2023 - Elsevier
Understanding the electrochemical reaction mechanisms of energy conversion and storage
systems is essential for improving their performance. Nuclear magnetic resonance (NMR) …

[HTML][HTML] 1H NMR spectroscopy of degraded perfluorosulfonic acid membranes: A simple methodology for detecting onset of degradation

Y Moon, RY Hwang, S Park, OH Han - Journal of Electroanalytical …, 2023 - Elsevier
Perfluorosulfonic acid (PFSA) polymer electrolyte membranes (PEMs) used in fuel cells
undergo chemical degradation when exposed to radicals formed during electrochemical …

Cation-exchange fluoropolymer membranes with the conjugate acid of 2, 3, 5, 6-tetrafluoroaniline as an alternative proton-exchange group

S Xu, W Sang, R Jiang, Y Gao - Journal of Fluorine Chemistry, 2019 - Elsevier
In this paper, we report the synthesis of perfluoro (2, 3, 5, 6-tetrafluoroanilinium sulfate)(PF
(TFA-H)) from Nafion™ via a free-radical desulfur coupling reaction, which utilizes TFA-H as …