Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt (II) complexes with zero-field hidden single-molecule magnet behaviour: the …
A Landart-Gereka, MM Quesada-Moreno… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The complexes [Co (L)] X· S (X= CoCl42−, S= CH3CN (1); X= ZnCl42−, S= CH3OH (2)),[Co
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
Largely enhancing the blocking energy barrier and temperature of a linear cobalt (II) complex through the structural distortion: a theoretical exploration
F Lu, WX Guo, YQ Zhang - Inorganic Chemistry, 2021 - ACS Publications
Complete-active-space self-consistent field and N-electron valence second-order
perturbation theory have both been employed to investigate the magnetic anisotropy of one …
perturbation theory have both been employed to investigate the magnetic anisotropy of one …
Assembly of air-stable copper (I) alkynide nanoclusters assisted by tripodal polydentate phosphoramide ligands
H Zhao, C Zhang, B Han, Z Wang, Y Liu, Q Xue… - Nature …, 2024 - nature.com
Copper (I) nanoclusters are attractive due to their potential applications, but their synthesis
remains challenging due to susceptibility to oxidation and the lack of mature synthetic …
remains challenging due to susceptibility to oxidation and the lack of mature synthetic …
Trigonal prismatic cobalt (II) single-ion magnets: Manipulating the magnetic relaxation through symmetry control
Two mononuclear trigonal prismatic Co (II) complexes [Co (tppm*)][BPh4] 2 (1) and [Co
(hpy)][BPh4] 2· 3CH2Cl2 (2)(tppm*= 6, 6′, 6 ″-(methoxymethanetriyl) tris (2-(1 H-pyrazol-1 …
(hpy)][BPh4] 2· 3CH2Cl2 (2)(tppm*= 6, 6′, 6 ″-(methoxymethanetriyl) tris (2-(1 H-pyrazol-1 …
Probing the axial distortion effect on the magnetic anisotropy of octahedral Co (II) complexes
Three mononuclear octahedral Co (II) complexes are reported,[Co (py) 4 (SCN) 2](1),[Co
(py) 4 (Cl) 2]· H2O (2), and [Co (py) 4 (Br) 2](3), that exhibit different distortions with …
(py) 4 (Cl) 2]· H2O (2), and [Co (py) 4 (Br) 2](3), that exhibit different distortions with …
Modern physical methods for the molecular design of single-molecule magnets
VV Novikov, YV Nelyubina - Russian Chemical Reviews, 2021 - iopscience.iop.org
Many paramagnetic metal complexes have emerged as unique magnetic materials (single-
molecule magnets), which behave as conventional magnets at the single-molecule level …
molecule magnets), which behave as conventional magnets at the single-molecule level …
Coligand effects on the field-induced double slow magnetic relaxation in six-coordinate cobalt (II) single-ion magnets (SIMs) with positive magnetic anisotropy
J Vallejo, M Viciano-Chumillas, F Lloret… - Inorganic …, 2019 - ACS Publications
Two mononuclear cobalt (II) compounds of formula [Co (dmphen) 2 (OOCPh)] ClO4·
1/2H2O· 1/2CH3OH (1) and [Co (dmbipy) 2 (OOCPh)] ClO4 (2)(dmphen= 2, 9-dimethyl-1, 10 …
1/2H2O· 1/2CH3OH (1) and [Co (dmbipy) 2 (OOCPh)] ClO4 (2)(dmphen= 2, 9-dimethyl-1, 10 …
Important role of intermolecular interaction in cobalt (II) single-ion magnet from single slow relaxation to double slow relaxation
ZB Hu, ZY Jing, MM Li, L Yin, YD Gao, F Yu… - Inorganic …, 2018 - ACS Publications
Two cobalt complexes with similar structures were synthesized using quinoline-2-carboxylic
acid (HL) as the ligand. Both complexes are six-coordinated in antitriangular prism …
acid (HL) as the ligand. Both complexes are six-coordinated in antitriangular prism …
Construction and magnetic study of a trigonal-prismatic cobalt (II) single-ion magnet
A new tripodal hexadentate ligand of tris [6-(1 H-pyrazol-1-yl) pyridin-2-yl] methanol (tppm)
was synthesized and explored for constructing the trigonal-prismatic cobalt (II) complex [Co …
was synthesized and explored for constructing the trigonal-prismatic cobalt (II) complex [Co …
Detailed electronic structure of a high-spin cobalt (II) complex determined from NMR and THz-EPR spectroscopy
AA Pavlov, J Nehrkorn, YA Pankratova… - Physical Chemistry …, 2019 - pubs.rsc.org
Here we report a combined use of THz-EPR and NMR spectroscopy for obtaining a detailed
electronic structure of a long-known high-spin complex, cobalt (II) bis [tris (pyrazolyl) borate] …
electronic structure of a long-known high-spin complex, cobalt (II) bis [tris (pyrazolyl) borate] …