Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Biological hydrogen with industrial potential: Improvement and prospection in biohydrogen production

W Chen, T Li, Y Ren, J Wang, H Chen… - Journal of Cleaner …, 2023 - Elsevier
Hydrogen is an important industrial material and ideal secondary energy. It is widely used in
petrochemical, electronics, metallurgy, food processing, fine organic synthesis, and clean …

The catalytic cycle of [FeFe] hydrogenase: A tale of two sites

JA Birrell, P Rodriguez-Macia, EJ Reijerse… - Coordination Chemistry …, 2021 - Elsevier
Ever since the discovery of hydrogenases over 90 years ago (Stephenson and Stickland,
1931), their structure and mechanism of action have been intensively investigated. Of the …

Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

AC Ghosh, C Duboc, M Gennari - Coordination Chemistry Reviews, 2021 - Elsevier
Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …

Molecular basis of the electron bifurcation mechanism in the [FeFe]-hydrogenase complex HydABC

A Katsyv, A Kumar, P Saura… - Journal of the …, 2023 - ACS Publications
Electron bifurcation is a fundamental energy coupling mechanism widespread in
microorganisms that thrive under anoxic conditions. These organisms employ hydrogen to …

Hydrogenase and nitrogenase: key catalysts in biohydrogen production

J Xuan, L He, W Wen, Y Feng - Molecules, 2023 - mdpi.com
Hydrogen with high energy content is considered to be a promising alternative clean energy
source. Biohydrogen production through microbes provides a renewable and immense …

Evidence for low-valent electronic configurations in iron–sulfur clusters

AC Brown, NB Thompson… - Journal of the American …, 2022 - ACS Publications
Although biological iron–sulfur (Fe–S) clusters perform some of the most difficult redox
reactions in nature, they are thought to be composed exclusively of Fe2+ and Fe3+ ions, as …

Genetic engineering contribution to developing cyanobacteria-based hydrogen energy to reduce carbon emissions and establish a hydrogen economy

GK Kamshybayeva, BD Kossalbayev… - International Journal of …, 2024 - Elsevier
Growing concerns over greenhouse gas emissions and energy insecurity caused by the
depletion of conventional fuels have led to a search for sustainable fuel alternatives. As an …

Probing Substrate Transport Effects on Enzymatic Hydrogen Catalysis: An Alternative Proton Transfer Pathway in Putatively Sensory [FeFe] Hydrogenase

PR Cabotaje, K Walter, A Zamader, P Huang, F Ho… - ACS …, 2023 - ACS Publications
[FeFe] hydrogenases, metalloenzymes catalyzing proton/dihydrogen interconversion, have
attracted intense attention due to their remarkable catalytic properties and (bio-) …

Enzymatic and bioinspired systems for hydrogen production

L Leone, G Sgueglia, S La Gatta, M Chino… - International Journal of …, 2023 - mdpi.com
The extraordinary potential of hydrogen as a clean and sustainable fuel has sparked the
interest of the scientific community to find environmentally friendly methods for its production …