Conspectus Fluorine-containing compounds are extensively involved in various fields
originating from intriguing and unique characteristics of fluorine atom; notably, in …

Oxidative addition and reductive elimination are key steps in a wide variety of catalytic
reactions mediated by transition-metal complexes. Historically, this reactivity has been …

Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …

The activation and functionalization of C–F bonds under mild conditions can serve as an
important tool for organic syntheses including the modification of pharmaceuticals and …

Selective C− F bond functionalization of perfluoalkyl units has huge potential towards
accessing functionalized organofluorinated compounds, but remains challenging due to the …

Transition-metal-catalyzed decarbonylation via carbon–carbon bond cleavage is an
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …

Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Transition-metal-catalyzed nucleophilic addition of organometallic reagents to polar
unsaturated substrates is one of the most important and powerful bond-forming strategies …

The gem-difluoroalkenes and related compounds have gained much attention from the
organic synthetic community due to their widespread applications as versatile fluorinated …

Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …