The concept of active site in heterogeneous catalysis

C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …

Opportunities and challenges in the development of advanced materials for emission control catalysts

AK Datye, M Votsmeier - Nature Materials, 2021 - nature.com
Advances in engine technologies are placing additional demands on emission control
catalysts, which must now perform at lower temperatures, but at the same time be robust …

Recent advances in hybrid metal oxide–zeolite catalysts for low-temperature selective catalytic reduction of NOx by ammonia

T Andana, KG Rappe, F Gao, J Szanyi… - Applied Catalysis B …, 2021 - Elsevier
A hybrid catalytic system comprised of metal oxide and Cu or Fe exchanged zeolite
components represents a potential advancement of state-of-the-art for selective catalytic …

Self-Defense Effects of Ti-Modified Attapulgite for Alkali-Resistant NOx Catalytic Reduction

Y Zhao, L Shi, Y Shen, J Zhou, Z Jia… - Environmental …, 2022 - ACS Publications
Nowadays, the serious deactivation of deNO x catalysts caused by alkali metal poisoning
was still a huge bottleneck in the practical application of selective catalytic reduction of NO x …

Solvation and mobilization of copper active sites in zeolites by ammonia: consequences for the catalytic reduction of nitrogen oxides

C Paolucci, JR Di Iorio, WF Schneider… - Accounts of chemical …, 2020 - ACS Publications
Conspectus Copper-exchanged chabazite (Cu-CHA) zeolites are catalysts used in diesel
emissions control for the abatement of nitrogen oxides (NO x) via selective catalytic …

The promoting/inhibiting effect of water vapor on the selective catalytic reduction of NOx

R Gui, Q Yan, T Xue, Y Gao, Y Li, T Zhu… - Journal of Hazardous …, 2022 - Elsevier
In the field of nitrogen oxides (NO x) abatement, developing selective catalytic reduction
(SCR) catalysts that can operate stably in the practical conditions remains a big challenge …

Self-Protected CeO2–SnO2@SO42–/TiO2 Catalysts with Extraordinary Resistance to Alkali and Heavy Metals for NOx Reduction

S Cai, T Xu, P Wang, L Han, S Impeng… - Environmental …, 2020 - ACS Publications
Reducing the poisoning effect of alkali and heavy metals over ammonia selective catalytic
reduction (NH3-SCR) catalysts is still an intractable issue, as the presence of K and Pb in fly …

Poisoning-Resistant NOx Reduction in the Presence of Alkaline and Heavy Metals over H-SAPO-34-Supported Ce-Promoted Cu-Based Catalysts

P Wang, L Yan, Y Gu, S Kuboon, H Li… - … science & technology, 2020 - ACS Publications
Selective catalytic reduction (SCR) of NO x using NH3 in the presence of alkaline and heavy
metals is still an issue in the application of a stationary source. Reported here is the rational …

Copper Site Motion Promotes Catalytic NOx Reduction under Zeolite Confinement

D Chen, A Khetan, H Lei, V Rizzotto… - Environmental …, 2023 - ACS Publications
Ammonia-mediated selective catalytic reduction (NH3-SCR) is currently the key approach to
abate nitrogen oxides (NO x) emitted from heavy-duty lean-burn vehicles. The state-of-art …

Revealing the Synergistic Deactivation Mechanism of Hydrothermal Aging and SO2 Poisoning on Cu/SSZ-13 under SCR Condition

Y Zhang, H Zhu, T Zhang, J Li, J Chen… - … Science & Technology, 2021 - ACS Publications
In real-world application, Cu/SSZ-13 simultaneously suffers severe deactivation from
hydrothermal aging and SO2 poisoning during the periodic regeneration of diesel …