For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …

Abstract Complexes of Group 2, 12, 13, 14, 15 and 16 elements with mono-, bi-, and poly-
dentate phosphine and arsine ligands (and including the very few examples of stibine and …

The carbonyl group is undoubtedly one of the most important functional groups in organic
chemistry, both in its role as reactive center for synthesis or derivatisation and as crucial …

The synthesis of mono‐NHC alane adducts of the type (NHC)⋅ AlH3 (NHC= Me2Im (1),
Me2ImMe (2), iPr2Im (3 and [D3]‐3), iPr2ImMe (4), Dipp2Im (10); Im= imidazolin‐2‐ylidene …

Tertiary amine adducts of alane show a diverse range of structures based on four and five
coordinate species, hydride bridging dimeric and polymeric species, and ionic species …

The precise size-and shape-controlled synthesis of monodisperse Al nanocrystals remains
an open challenge, limiting their utility for numerous applications that would take advantage …

The reaction between sterically crowded, dimeric, arylalane (H2AlMes*) 2 and some aryl
amines, phosphines, or arsines are described. Treatment of (H2AlMes*) 2 (Mes*= 2, 4, 6-(t …

Organoaluminum compounds have found numerous applications in organic synthesis. 1
Many of the reaction characteristics of organoaluminums associated with the availability of …

Thermally robust expanded ring carbene adducts of AlH3 have been synthesized with a
view to probing their ligating abilities via Al–H σ-bond coordination. While κ2 binding to the …

Two aspects of Group 13 metal chemistry are surveyed in the light of recent research,
particularly that reported in the period 1992–1998. The first concerns compounds containing …