Quantum Chemical Interrogation of Reactions Promoted by Dirhodium Tetracarboxylate Catalysts─ Mechanism, Selectivity, and Nonstatistical Dynamic Effects

DJ Tantillo - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Rh2L4 catalysts have risen in popularity in the world of organic synthesis, being
used to accomplish a variety of reactions, including C–H insertion and cyclopropanation …

Cs2CO3 Promoted [4 + 2] Cycloaddition of 1,6-Enynes: An Approach to Tetrahydro-1H-benzo-f-isoindole Isomers

X Wang, J Yin, W Mao, Z Wang, S Wu, Y You - Organic Letters, 2024 - ACS Publications
A Cs2CO3-promoted [4+ 2] cycloaddition of 1, 6-enynes under mild reaction conditions has
been developed. This protocol provides a facile approach to a series of tetrahydro-1 H …

Síntese de derivados de γ-lactamas, Δ1-pirrolinas e pirróis a partir de chalconas empregando aziridinas e 2H-azirinas

LSR Martelli - 2024 - repositorio.ufscar.br
2-MeTHF: 2-metiltetraidrofurano ACN: acetonitrila AcOEt: acetato de etila BocNHOTs: N-Boc-
O-tosilhidroxilamina DABCO: 1, 4-diazobiciclo [2, 2, 2] octano DBU: 1, 8-diazobiciclo [5, 4, 0] …

Facile Generation of ortho-Quinodimethanes Toward Polycy-clic Compounds

K Inagaki, Y Onozawa, Y Fukuhara, D Yokogawa… - 2024 - chemrxiv.org
The Diels–Alder reaction is a cornerstone of organic synthesis, enabling the construction of
complex molecular archi-tectures through the cycloaddition of a diene and a dienophile …

Metal‐Catalyzed Coupling of N‐Tosylhydrazones with Compounds Containing C−H/Heteroatom‐H Bonds

Akanksha, AK Singh, A Asthana, R Ravi… - Asian Journal of … - Wiley Online Library
The present review covers various advances in the field of metal‐catalyzed coupling of N‐
tosylhydrazones with compounds containing C− H/heteroatom‐H bonds, including transition …