High-yield, green and scalable methods for producing MOF-303 for water harvesting from desert air

Z Zheng, HL Nguyen, N Hanikel, KKY Li, Z Zhou… - Nature …, 2023 - nature.com
Metal–organic frameworks (MOFs) are excellent candidates for water harvesting from desert
air. MOF-303 (Al (OH)(PZDC), where PZDC is 1-H-pyrazole-3, 5-dicarboxylate), a robust and …

Water adsorption in MOFs: structures and applications

B Zhang, Z Zhu, X Wang, X Liu… - Advanced Functional …, 2023 - Wiley Online Library
Metal–organic frameworks (MOFs) are superior sorbents for water adsorption‐based
applications. The unique step‐like water isotherm at a MOF‐specific relative pressure allows …

Tunable low–relative humidity and high–capacity water adsorption in a bibenzotriazole metal–organic framework

D Alezi, JJ Oppenheim, PJ Sarver… - Journal of the …, 2023 - ACS Publications
Materials capable of selectively adsorbing or releasing water can enable valuable
applications ranging from efficient humidity and temperature control to the direct …

Water harvesting at the single-crystal level

A Fuchs, F Knechtel, H Wang, Z Ji… - Journal of the …, 2023 - ACS Publications
Metal–organic frameworks (MOFs) have emerged as a class of porous materials with facile
uptake and release of water, turning them into excellent substrates for real-world …

Reticular Synthesis of Metal‐Organic Frameworks by 8‐Connected Quadrangular Prism Ligands for Water Harvesting

W Liu, E Wu, B Yu, Z Liu, K Wang, D Qi… - Angewandte …, 2023 - Wiley Online Library
Utilization of rigid, highly connected organic linkers is critical for the reticular synthesis of
functional metal–organic frameworks (MOFs). However, highly‐stable MOFs (eg Al/Cr/Zr …

Ultrafast Water H-Bond Rearrangement in a Metal–Organic Framework Probed by Femtosecond Time-Resolved Infrared Spectroscopy

ML Valentine, G Yin, JJ Oppenheim… - Journal of the …, 2023 - ACS Publications
We investigated the water H-bond network and its dynamics in Ni2Cl2BTDD, a prototypical
MOF for atmospheric water harvesting, using linear and ultrafast IR spectroscopy. Utilizing …

Bridging materials innovations to sorption-based atmospheric water harvesting devices

Y Zhong, L Zhang, X Li, B El Fil, CD Díaz-Marín… - Nature Reviews …, 2024 - nature.com
The atmosphere contains 13,000 trillion litres of water, and it is a natural resource available
anywhere. Sorption-based atmospheric water harvesting (SAWH) is capable of extracting …

Ionothermal Synthesis of Metal‐Organic Frameworks Using Low‐Melting Metal Salt Precursors

TJ Azbell, TA Pitt, MM Bollmeyer… - Angewandte Chemie …, 2023 - Wiley Online Library
Metal‐organic frameworks (MOFs) are porous, crystalline materials constructed from organic
linkers and inorganic nodes with myriad potential applications in chemical separations …

A continuous flow chemistry approach for the ultrafast and low-cost synthesis of MOF-808

S Bagi, S Yuan, S Rojas-Buzo, Y Shao-Horn… - Green …, 2021 - pubs.rsc.org
Metal–organic frameworks (MOFs) are promising materials for a wide range of applications
given their chemical stability and structural tunability. Most traditional MOF synthesis …

Study of the scale-up effect on the water sorption performance of MOF materials

Z Chen, Z Shao, Y Tang, F Deng, S Du… - ACS Materials …, 2022 - ACS Publications
Numerous adsorbents have been developed to extract water from air by sorption-based
atmospheric water harvesting (SAWH). However, laboratory-level studies on the water …