The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but
limited to specific substrate classes. Here, we report electroreductive XEC of previously …

Conspectus Transition-metal catalyzed cross-coupling reactions are fundamental reactions
in organic chemistry, facilitating strategic bond formations for accessing natural products …

Energy transfer can leverage the enormous potential of excited-state reactivity. Through"
indirect excitation" of substrates, otherwise elusive reactivity modes can be switched on …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

The combined use of reaction kinetic analysis, ultrafast spectroscopy, and stoichiometric
organometallic studies has enabled the elucidation of the mechanistic underpinnings to a …

Aryl amination is an essential transformation for medicinal, process, and materials chemistry.
In addition to classic Buchwald–Hartwig amination conditions, blue-light-driven …

The formation of C‐heteroatom bonds represents an important type of bond‐forming
reaction in organic synthesis and often provides a fast and efficient access to privileged …

Cross-coupling reactions are among the most important transformations in modern organic
synthesis,–. Although the range of reported (het) aryl halides and nucleophile coupling …