Cyclopropanation strategies in recent total syntheses

C Ebner, EM Carreira - Chemical reviews, 2017 - ACS Publications
Complex molecular architectures containing cyclopropanes present significant challenges
for any synthetic chemist. This review aims to highlight the strategic considerations for …

Recent advances in the total synthesis of cyclopropane-containing natural products

DYK Chen, RH Pouwer, JA Richard - Chemical Society Reviews, 2012 - pubs.rsc.org
In this tutorial review, recent advances in the synthesis of cyclopropane-containing natural
products are discussed, highlighting the application of novel synthetic methodologies and …

Chloranthus genome provides insights into the early diversification of angiosperms

X Guo, D Fang, SK Sahu, S Yang, X Guang… - Nature …, 2021 - nature.com
Chloranthales remain the last major mesangiosperm lineage without a nuclear genome
assembly. We therefore assemble a high-quality chromosome-level genome of Chloranthus …

Chemistry and bioactivity of lindenane sesquiterpenoids and their oligomers

J Luo, D Zhang, P Tang, N Wang, S Zhao… - Natural Product …, 2024 - pubs.rsc.org
Covering: 1925 to July 2023 Among the sesquiterpenoids with rich structural diversity and
potential bioactivities, lindenane sesquiterpenoids (LSs) possess a characteristic cis, trans …

Enantioselective palladium/copper-catalyzed C–C σ-bond activation synergized with Sonogashira-type C (sp 3)–C (sp) cross-coupling alkynylation

FN Sun, WC Yang, XB Chen, YL Sun, J Cao, Z Xu… - Chemical …, 2019 - pubs.rsc.org
The Sonogashira-type cross-coupling reaction is one of the most significant alkynylation
transformations in organic chemistry. However, highly enantioselective alkynylation via the …

Pd‐Catalyzed Enantioselective Ring Opening/Cross‐Coupling and Cyclopropanation of Cyclobutanones

J Cao, L Chen, FN Sun, YL Sun… - Angewandte Chemie …, 2019 - Wiley Online Library
A palladium‐catalyzed enantioselective sequential ring‐opening/cross‐coupling of
cyclobutanones is disclosed that provides chiral indanones bearing C3‐quaternary …

Bioinspired total synthesis of bolivianine: A Diels–Alder/intramolecular hetero-Diels–Alder cascade approach

C Yuan, B Du, L Yang, B Liu - Journal of the American Chemical …, 2013 - ACS Publications
We report the first total synthesis of bolivanine in a 14-step pathway involving the synthesis
of onoseriolide. Our synthesis features a palladium-catalyzed intramolecular …

Trichloranoids A–D, antimalarial sesquiterpenoid trimers from Chloranthus spicatus

JS Zhou, QF Liu, FM Zimbres, JH Butler… - Organic Chemistry …, 2021 - pubs.rsc.org
Four new lindenane sesquiterpenoid trimers, designated as trichloranoids A–D (1–4), along
with a known analogue (5) were isolated from Chloranthus spicatus. Their structures were …

Natural disesquiterpenoids: an update

LF Ma, YL Chen, WG Shan, ZJ Zhan - Natural Product Reports, 2020 - pubs.rsc.org
Covering: July 2010 to August 2019. Previous review: Nat. Prod. Rep., 2011, 28, 594 The
review covers recent progress on the isolation, identification, bioactivity and biomimetic …

Natural sesquiterpenoids

BM Fraga - Natural product reports, 2012 - pubs.rsc.org
Covering: 2011. Previous review: Nat. Prod. Rep. 2011, 28, 1580. This review covers the
isolation, structural determination, synthesis and chemical and microbiological …