Nanoscale molecular rectifiers

R Gupta, JA Fereiro, A Bayat, A Pritam… - Nature Reviews …, 2023 - nature.com
The use of molecules bridged between two electrodes as a stable rectifier is an important
goal in molecular electronics. Until recently, however, and despite extensive experimental …

Coherence in Chemistry: Foundations and Frontiers

JD Schultz, JL Yuly, EA Arsenault, K Parker… - Chemical …, 2024 - ACS Publications
Coherence refers to correlations in waves. Because matter has a wave-particle nature, it is
unsurprising that coherence has deep connections with the most contemporary issues in …

[PDF][PDF] Signatures of quantum interference effects on charge transport through a single benzene ring

CR Arroyo, S Tarkuc, R Frisenda… - Angewandte Chemie …, 2013 - academia.edu
Until recently, single-molecule conduction experiments have mostly been described in terms
of a nonresonant tunneling process where the molecule acts as a tunneling barrier.[1–3] In …

Progress with molecular electronic junctions: meeting experimental challenges in design and fabrication

RL McCreery, AJ Bergren - Advanced materials, 2009 - Wiley Online Library
Molecular electronics seeks to incorporate molecular components as functional elements in
electronic devices. There are numerous strategies reported to date for the fabrication …

Understanding quantum interference in coherent molecular conduction

GC Solomon, DQ Andrews, T Hansen… - The Journal of …, 2008 - pubs.aip.org
Theory and experiment examining electron transfer through molecules bound to electrodes
are increasingly focused on quantities that are conceptually far removed from current …

Evidence for quantum interference in SAMs of arylethynylene thiolates in tunneling junctions with eutectic Ga–In (EGaIn) top-contacts

D Fracasso, H Valkenier, JC Hummelen… - Journal of the …, 2011 - ACS Publications
This paper compares the current density (J) versus applied bias (V) of self-assembled
monolayers (SAMs) of three different ethynylthiophenol-functionalized anthracene …

Quantum interference in acyclic systems: Conductance of cross-conjugated molecules

GC Solomon, DQ Andrews, RH Goldsmith… - Journal of the …, 2008 - ACS Publications
We calculate that significant quantum interference effects can be observed in elastic electron
transport through acyclic molecules. Interference features are evident in the transmission …

Solution-based intramolecular singlet fission in cross-conjugated pentacene dimers

J Zirzlmeier, R Casillas, SR Reddy, PB Coto… - Nanoscale, 2016 - pubs.rsc.org
We show unambiguous and compelling evidence by means of pump–probe experiments,
which are complemented by calculations using ab initio multireference perturbation theory …

A critical perspective on molecular electronic junctions: there is plenty of room in the middle

RL McCreery, H Yan, AJ Bergren - Physical Chemistry Chemical …, 2013 - pubs.rsc.org
The promise of molecular electronic devices stems from the possibilities offered by the rich
electronic structure of organic molecules. The use of molecules as functional components in …

Controlling electron transfer in donor− bridge− acceptor molecules using cross-conjugated bridges

AB Ricks, GC Solomon, MT Colvin… - Journal of the …, 2010 - ACS Publications
Photoinitiated charge separation (CS) and recombination (CR) in a series of donor− bridge−
acceptor (D− B− A) molecules with cross-conjugated, linearly conjugated, and saturated …