Recent advances in the selective oxidation of glycerol to value-added chemicals via photocatalysis/photoelectrocatalysis

Y Liu, B Zhang, D Yan, X Xiang - Green Chemistry, 2024 - pubs.rsc.org
Glycerol, as the major by-product of biodiesel, is a highly versatile molecule with three
similar hydroxyl groups. Recently, great efforts have been mode to finding active catalysts …

Sustainable catalytic oxidation of glycerol: a review

X Hu, J Lu, Y Liu, L Chen, X Zhang, H Wang - Environmental Chemistry …, 2023 - Springer
Valorization of biomass-derived feedstocks for the supply of high-value chemicals, clean fuel
and electricity is gaining importance in the context of the circular economy. In particular, raw …

Electrocatalytic upcycling of biomass and plastic wastes to biodegradable polymer monomers and hydrogen fuel at high current densities

Y Yan, H Zhou, SM Xu, J Yang, P Hao… - Journal of the …, 2023 - ACS Publications
Transformation of biomass and plastic wastes to value-added chemicals and fuels is
considered an upcycling process that is beneficial to resource utilization. Electrocatalysis …

Yttrium-doped cobalt-based metal–organic frameworks for selective electrooxidation of glycerol coupled with hydrogen production

Y Xu, Q Zhou, T Liu, T Ren, H Yu, K Deng… - Chemical …, 2023 - pubs.rsc.org
A facile strategy was developed for one-step synthesis of yttrium (Y)-doped cobalt-based
metal–organic framework (CoY-MOF) nanosheet arrays. It was demonstrated that in situ …

How to change the reaction chemistry on nonprecious metal oxide nanostructure materials for electrocatalytic oxidation of biomass‐derived glycerol to renewable …

LS Oh, M Park, YS Park, Y Kim, W Yoon… - Advanced …, 2023 - Wiley Online Library
Au and Pt are well‐known catalysts for electrocatalytic oxidation of biomass‐derived
glycerol. Although some nonprecious‐metal‐based materials to replace the costly Au and Pt …

[HTML][HTML] Amorphous antimony oxide as reaction pathway modulator toward electrocatalytic glycerol oxidation for selective dihydroxyacetone production

D Kim, WG Lim, Y Kim, LS Oh, S Kim, JH Park… - Applied Catalysis B …, 2023 - Elsevier
Achievement of an efficient and stable electrocatalytic glycerol oxidation reaction (EGOR) is
limited by a lack of strategies for designing advanced electrocatalysts that satisfy the desired …

Recent advances in glycerol valorization via electrooxidation: Catalyst, mechanism and device

J Wu, X Yang, M Gong - Chinese Journal of Catalysis, 2022 - Elsevier
Glycerol is one of the most important biomass-based platform molecules, massively
produced as a by-product in the biodiesel industry. Its high purification cost from the crude …

Anode‐Electrolyte Interfacial Acidity Regulation Enhances Electrocatalytic Performances of Alcohol Oxidations

B Huang, J Yan, Z Li, L Chen… - Angewandte Chemie …, 2024 - Wiley Online Library
The local acidity at the anode surface during electrolysis is apparently stronger than that in
bulk electrolyte due to the deprotonation from the reactant, which leads to the deteriorated …

Anodic glycerol oxidation to formate facilitating cathodic hydrogen evolution with earth-abundant metal oxide catalysts

G Wu, X Dong, J Mao, G Li, C Zhu, S Li, A Chen… - Chemical Engineering …, 2023 - Elsevier
Substituting sluggish oxygen evolution reaction (OER) with glycerol electrooxidation
reaction (GER) to formate is a promising strategy for addressing glycerol overproduction and …

Ligand Hybridization for Electro‐reforming Waste Glycerol into Isolable Oxalate and Hydrogen

J Wu, X Liu, Y Hao, S Wang, R Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
The electro‐reforming of glycerol is an emerging technology of simultaneous hydrogen
production and biomass valorization. However, its complex reaction network and limited …