Dehydrogenation of alkanes and aliphatic groups by pincer-ligated metal complexes

A Kumar, TM Bhatti, AS Goldman - Chemical reviews, 2017 - ACS Publications
The alkyl group is the most common component of organic molecules and the most difficult
to selectively functionalize. The development of catalysts for dehydrogenation of alkyl …

Organic synthesis involving iridium-catalyzed oxidation

T Suzuki - Chemical reviews, 2011 - ACS Publications
Oxidation of organic compounds is one of the most fundamental technologies for organic
synthesis. Traditional methods, however, use stoichiometric quantities of toxic heavy metal …

Bis-Tridentate Ir (III) Complexes with Nearly Unitary RGB Phosphorescence and Organic Light-Emitting Diodes with External Quantum Efficiency Exceeding 31%.

CY Kuei, WL Tsai, B Tong, M Jiao, WK Lee… - … (Deerfield Beach, Fla …, 2016 - europepmc.org
A new class of neutral bis-tridentate Ir (III) metal complexes that show nearly unitary red,
green, and blue emissions in solution is prepared and employed for the fabrication of both …

Emissive bis-tridentate Ir (III) metal complexes: Tactics, photophysics and applications

Y Chi, TK Chang, P Ganesan, P Rajakannu - Coordination Chemistry …, 2017 - Elsevier
This review is an update on current advances in metal complexes with d 6-electronic
configuration and bearing two tridentate chelates. We first elaborate the basic properties of …

A leap forward in iridium–NHC catalysis: new horizons and mechanistic insights

M Iglesias, LA Oro - Chemical Society Reviews, 2018 - pubs.rsc.org
This review summarises the most recent advances in Ir–NHC catalysis while revisiting all the
classical reactions in which this type of catalyst has proved to be active. The influence of the …

Selective catalytic transfer dehydrogenation of alkanes and heterocycles by an iridium pincer complex

W Yao, Y Zhang, X Jia, Z Huang - Angewandte Chemie, 2014 - Wiley Online Library
Catalytic alkane dehydrogenation is a reaction with tremendous potential for application. We
describe a highly active PSCOP‐pincer iridium catalyst for transfer dehydrogenation of cyclic …

Bis-tridentate Ir (III) Phosphors and Blue Hyperphosphorescence with Suppressed Efficiency Roll-Off at High Brightness

J Yan, ZH Qu, DY Zhou, SM Yiu, Y Qin… - … Applied Materials & …, 2024 - ACS Publications
Narrowband blue emitters are indispensable in achieving ultrahigh-definition OLED displays
that satisfy the stringent BT 2020 standard. Hereby, a series of bis-tridentate Ir (III) …

Visible Light Induced Rhodium (I)‐Catalyzed C− H Borylation

J Thongpaen, R Manguin, V Dorcet, T Vives… - Angewandte …, 2019 - Wiley Online Library
An efficient visible light induced rhodium (I)‐catalyzed regioselective borylation of aromatic
C− H bonds is reported. The photocatalytic system is based on a single NHC− RhI complex …

NHC-based pincer ligands: carbenes with a bite

RE Andrew, L González-Sebastián, AB Chaplin - Dalton transactions, 2016 - pubs.rsc.org
In this frontier article we overview the emergence and scope of NHC-based CCC and CNC
pincer systems, ie complexes containing mer-tridentate ligands bearing two NHC donor …

Reactivity of Iridium Complexes of a Triphosphorus-Pincer Ligand Based on a Secondary Phosphine. Catalytic Alkane Dehydrogenation and the Origin of Extremely …

BM Gordon, N Lease, TJ Emge… - Journal of the …, 2022 - ACS Publications
The selective functionalization of alkanes and alkyl groups is a major goal of chemical
catalysis. Toward this end, a bulky triphosphine with a central secondary phosphino group …