In recent decades, increasing efforts have been made for the development of more efficient
and sustainable methods for the functionalization of saturated cyclic amines. This is mainly …

The widely used C–H functionalization strategies and some complexities in the Pd-catalyzed
chemical transformations were analyzed. It was emphasized that in the course of catalysis …

The generation of carbon radicals by halogen-atom and group transfer reactions is generally
achieved using tin and silicon reagents that maximize the interplay of enthalpic …

Saturated heterocycles are found in numerous therapeutics and bioactive natural products
and are abundant in many medicinal and agrochemical compound libraries. To access new …

Herein, we disclose a straightforward, robust, and simple route to access β‐substituted
desaturated cyclic amines via an electrochemically driven desaturative β‐functionalization of …

Cyclic amines are ubiquitous core structures of bioactive natural products and
pharmaceutical drugs. Although the site-selective abstraction of C–H bonds is an attractive …

Saturated N-heterocycles are prevalent in biologically active molecules and are increasingly
attractive scaffolds in the development of new pharmaceuticals. Unlike their aromatic …

Access to enantiomerically pure chiral mono-and disubstituted piperidines and pyrrolidines
has been achieved using a biocatalytic cascade involving carboxylic acid reductase (CAR) …

Primary amines are often cheap, naturally occurring, and chemically diverse starting
materials. For these reasons, deaminative functionalization of amines has emerged as an …

Whereas there is a significant interest in the rapid construction of diversely substituted
saturated heterocycles, direct and modular access is currently limited to the mono-, 2, 3-, or …