Solar‐to‐H2O2 Catalyzed by Covalent Organic Frameworks

Z Yong, T Ma - Angewandte Chemie, 2023 - Wiley Online Library
Benefiting from the excellent structural tunability, robust framework, ultrahigh porosity, and
rich active sites, covalent organic frameworks (COFs) are widely recognized as promising …

Photocatalytic H2O2 production systems: design strategies and environmental applications

Z Chen, D Yao, C Chu, S Mao - Chemical Engineering Journal, 2023 - Elsevier
Abstract Hydrogen peroxide (H 2 O 2) is an environmentally friendly versatile oxidant, which
has been used in chemical industry, medical, energy, and environmental fields …

Dual donor-acceptor covalent organic frameworks for hydrogen peroxide photosynthesis

C Qin, X Wu, L Tang, X Chen, M Li, Y Mou, B Su… - Nature …, 2023 - nature.com
Constructing photocatalytically active and stable covalent organic frameworks containing
both oxidative and reductive reaction centers remain a challenge. In this study …

Covalent organic frameworks for direct photosynthesis of hydrogen peroxide from water, air and sunlight

F Liu, P Zhou, Y Hou, H Tan, Y Liang, J Liang… - Nature …, 2023 - nature.com
Solar-driven photosynthesis is a sustainable process for the production of hydrogen
peroxide, the efficiency of which is plagued by side reactions. Metal-free covalent organic …

Cooperative Coupling of H2O2 Production and Organic Synthesis over a Floatable Polystyrene‐Sphere‐Supported TiO2/Bi2O3 S‐Scheme Photocatalyst

B He, Z Wang, P Xiao, T Chen, J Yu… - Advanced …, 2022 - Wiley Online Library
Cooperative coupling of photocatalytic H2O2 production with organic synthesis has an
expansive perspective in converting solar energy into storable chemical energy. However …

Oxidation‐Reduction Molecular Junction Covalent Organic Frameworks for Full Reaction Photosynthesis of H2O2

JN Chang, Q Li, JW Shi, M Zhang, L Zhang… - Angewandte …, 2023 - Wiley Online Library
The full reaction photosynthesis of H2O2 that can combine water‐oxidation and oxygen‐
reduction without sacrificial agents is highly demanded to maximize the light‐utilization and …

Piperazine-Linked Metalphthalocyanine Frameworks for Highly Efficient Visible-Light-Driven H2O2 Photosynthesis

Q Zhi, W Liu, R Jiang, X Zhan, Y Jin… - Journal of the …, 2022 - ACS Publications
Artificial photosynthesis of H2O2 from O2 reduction provides an energy-saving, safe, and
green approach. However, it is still critical to develop highly active and selective 2e–oxygen …

Integrating Bifunctionality and Chemical Stability in Covalent Organic Frameworks via One-Pot Multicomponent Reactions for Solar-Driven H2O2 Production

P Das, G Chakraborty, J Roeser, S Vogl… - Journal of the …, 2023 - ACS Publications
Multicomponent reactions (MCRs) can be used to introduce different functionalities into
highly stable covalent organic frameworks (COFs). In this work, the irreversible three …

Covalent Organic Frameworks Containing Dual O2 Reduction Centers for Overall Photosynthetic Hydrogen Peroxide Production

D Chen, W Chen, Y Wu, L Wang, X Wu… - Angewandte Chemie …, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) are highly desirable for achieving high‐efficiency
overall photosynthesis of hydrogen peroxide (H2O2) via molecular design. However …

Thiophene‐Containing Covalent Organic Frameworks for Overall Photocatalytic H2O2 Synthesis in Water and Seawater

JY Yue, LP Song, YF Fan, ZX Pan… - Angewandte Chemie …, 2023 - Wiley Online Library
H2O2 is a significant chemical widely utilized in the environmental and industrial fields, with
growing global demand. Without sacrificial agents, simultaneous photocatalyzed H2O2 …